Thématiques de Recherche
- Fluor et soufre: Sulfoniums, sulfilimines, sulfoximines, sulfilimino iminiums
- Perfluoroalkylation par catalyse photoredox – Nouveaux réactifs
- Nouveaux substituants fluorés émergents associant chaines perfluorées et chalcogènes
- Nouveaux milieux réactionnels eco-compatibles (liquides ioniques)
- Préparation de ligands perfluorés pour des solides poreux
- Analogues fluorés de composés naturels ou à visée thérapeutique
Contact
Disciplines
- Chimie77
- Chimie/Chimie organique48
- Chimie/Catalyse4
- Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph]3
- Sciences du Vivant [q-bio]3
- Chimie/Matériaux2
- Chimie/Chimie théorique et/ou physique2
- Physique [physics]2
- Chimie/Chimie analytique1
- Chimie/Chimie inorganique1
- Chimie/Autre1
- Chimie/Polymères1
- Chimie/Chimie thérapeutique1
- Informatique [cs]1
- Mathématiques [math]1
- Science non linéaire [physics]1
- Physique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]1
- Physique [physics]/Matière Condensée [cond-mat]/Matière Molle [cond-mat.soft]1
- Économie et finance quantitative [q-fin]1
- Sciences cognitives1
- Sciences de l'environnement1
- Planète et Univers [physics]1
- Sciences du Vivant [q-bio]/Biochimie, Biologie Moléculaire/Biochimie [q-bio.BM]1
- Sciences du Vivant [q-bio]/Autre [q-bio.OT]1
- Sciences de l'Homme et Société1
- Sciences de l'ingénieur [physics]1
- Statistiques [stat]1
Mots-clefs
Acidity Alkylation Chemical structure Copper Cross-coupling Electron transfer Fluorine Green chemistry Halogenation Ionic liquids Microwaves Nucleophilic substitution Photoredox catalysis Selenium Sulfilimines Sulfoximines Sulfur Sulfur heterocycles Synthetic methods Trifluoromethylselenolation
- Fluorine25
- Sulfoximines10
- Sulfur10
- Selenium7
- Synthetic methods7
- Ionic liquids6
- Copper4
- Nucleophilic substitution4
- Sulfilimines4
- Green chemistry3
- Halogenation3
- Microwaves3
- Photoredox catalysis3
- Sulfur heterocycles3
- Trifluoromethylselenolation3
- Acidity2
- Alkylation2
- Chemical structure2
- Cross-coupling2
- Electron transfer2
- Electrophiles2
- Electrophilic trifluoromethylation2
- Fluorination2
- Heck reaction2
- Homogeneous catalysis2
- Ionization2
- Nitriles2
- Nitrogen2
- Oxidation2
- Palladium2
- Photocatalysis2
- Reaction mechanisms2
- Sulfonium salts2
- Sulfoxides2
- Sulfoximine2
- Trifluoromethyl2
- 13C NMR1
- 19F NMR1
- 29Si NMR1
- 77Se NMR1
- ACETYLENES1
- ACTIVATION1
- ALPHA-FLUOROSULFOXIMINES1
- Acetylene equivalent1
- Acylation1
- Adduit de spin1
- Agrochimie1
- Alcene1
- Alcohol1
- Alcohols1
- Aldehydes1
- Alkene1
- Alkoxy C-O bonds carbonyloxy fluoroalkoxy photoredox catalysis radicals1
- Alkynes1
- Allylic trifluoromethylation1
- Amides1
- Anhydrides1
- Anions1
- Antimony trifluoride1
- Arylations1
- BENZENE DIMER1
- BROMIDES1
- Binding1
- Biomass1
- CO21
- Carbamoylation1
- Catalysis1
- Catalyst1
- Ccarbotrifluoromethylthiolation1
- Charge transfer1
- Chimie organique1
- Chlorination1
- Chromophores1
- Cleavage by chlorine1
- Cleavage reactions1
- Cyanides1
- C–H activation1
- C−H functionalization1
- DIFLUOROMETHYLATION1
- Dealkylation1
- Decarbonylation1
- Desulfurization1
- Diels-Alder reactions1
- Difluoromethylation1
- Dihydrogen peroxide1
- Dualphotocatalysis1
- EPOXIDES1
- EPR1
- EPR spectroscopy1
- EXPLANATION1
- Electron-deficient compounds1
- Electroreduction1
- Elimination1
- Eliminations1
- Enaminones1
- Enantiomers1
- Enantiomers Fluorine SFC Sulfilimines Sulfoximines1
- Enones1
- Environmentally Compatible Access to α-Trifluoromethylselenoenones Fluorine1
- Estradiol receptor alpha1
- Ethers1
- FLUOROEPOXIDES1
- Fluor1
- Fluoride anion1
- Fluorinated alkyl halides1
- Fluorinated compounds1
- Fluorinated ligands1
- Fluorinated ligands • Azamacrocycles • Biphasic catalysis • Oxidation • Michael addition1
- Fluorinated substituents1
- Fluorinated sulfoximines1
- Fluorination chlorination oxidative desulfurization-fluorination antimony trifluoride hydrogen fluoride trifluoromethyl ethers1
- Fluorine·Heterocycles1
- Glycosides1
- HYBRID FRAMEWORKS1
- Hydrogen fluoride1
- Hypervalent compounds1
- Hypervalent iodine1
- Imination of sulfoxides1
- Indoles1
- Intermédiaire radicalaire1
- Iodine1
- Ionic liquid1
- Iron1
- Isocoumarins1
- Isotope-induced chemical shifts1
- Ketones1
- Ligands1
- Lignin1
- METAL-ORGANIC-FRAMEWORK1
- METHANE1
- MOFS1
- Mechanistic studies1
- Metal-free1
- Mixtures1
- Morita-Baylis-Hillman1
- Morita-Baylis-Hillman reaction1
- Multi-component reactions1
- Multiple bonds1
- Mécanisme de la réaction1
- Mécanisme réactionnel spin trapping1
- Médicaments1
- N-bridged sulfoximines1
- NMR1
- NUCLEOPHILES1
- Nmr spectrometry1
- Organic solvent1
- Organocatalysis1
- Organofluorine compounds1
- Oxidative desulfurization-fluorination1
- Oxygen heterocycles1
- Palladiumii1
- Paramagnetic resonance1
- Perfluoroalkyl radicals1
- Perfluoroalkyl steroid1
- Perfluoroalkylation1
- Perfluoroalkylselenolation1
- Phenyls1
- Photocatalyse1
- Polyoxometalate1
- Potassium1
- Pyrimidones1
- REAGENT1
- RPE1
- Radical1
- Radical intermediate1
- Radical ions1
- Radical pathway1
- Radicals1
- Reaction mechanism1
- Reaction products1
- Reactivity1
- Rearrangement1
- Redox potential1
- Redox reactions1
- Reduction1
- Regioselectivity1
- Rheology1
- Résonance paramagnétique électronique1
- S-Perfluoroalkylated sulfoximines1
- S-arylsulfoximines1
- SFC1
- SOLIDS1
- STRATEGY1
- Scale-up1
- Selenium derivatives1
- Selenocyanation1
- Selenyl chloride1
- Silicon1
- Sodium1
- Sodium formate1
- Sodium sulfite1
- Solvant organique1
- Solvents1
- Spectrométrie rmn1
- Spin adduct1
- Spin trapping1
- Stabilization1
- Substituents1
- Sulfides1
- Sulfilimino iminium1
Auteurs
Magnier Emmanuel134
Dagousset Guillaume44
Anselmi Elsa28
Pégot Bruce14
Barthelemy Anne-Laure12
Blazejewski Jean-Claude12
Diter Patrick12
Pegot Bruce11
Macé Yohan10
Diter Patrick10
Billard Thierry10
Wakselman Claude8
Marrot Jérôme8
Duhail Thibaut7
Pégot Bruce7
Urban Céline7
Vo-Thanh Giang7
Blazejewski Jean‐claude6
Bourdreux Flavien6
Grollier Kevin6
Bournaud Chloée5
Bouvet Sébastien5
Briand Marina5
Le Thanh-Nghi5
Pradet Charlotte5
de Zordo-Banliat Arnaud5
Toffano Martial5
Maurin Guillaume5
Vanthuyne Nicolas5
Serre Christian5
Devic Thomas5
Horcajada Patricia5
Carboni Aude5
Anselmi Elsa4
Banoun Camille4
Langlois Yves4
Yagupolskii Yurii4
Agouridas Vangelis4
Tuccio Béatrice4
Masson Géraldine4
Messaoudi Samir4
Floquet Sébastien4
Bouvet Sebastien3
Chaabouni Slim3
Cleeren Anny3
Dagousset Guillaume3
Glachet Thomas3
Goumont Régis3
Kizilian Elyane3
Larpent Chantal3
Leclercq Guy3
Togni Antonio3
Masson Geraldine3
Tordeux Marc3
Reboul Vincent3
Barthelemy Anne‐laure2
Cadoret Frédéric2
Elkaim Erik2
Ferey Gerard2
Filinchuk Y.2
Goujon Gabriel2
Hannedouche Jérôme2
Heurtaux Daniela2
Kalim Jorna2
Laïos Ioanna2
Levitre Guillaume2
Martinetto Yohan2
Popkin Matthew2
Simon Cédric2
Sokolenko Liubov2
Terrier François2
Toffano Martial2
Vors Jean-Pierre2
Zhu Mingxiang2
Zriba Riadh2
de Castries Augustin2
Jeftic Jelena2
Goncalves Anne-Marie2
Li Yang2
Cuadros Sara2
Paut Julien2
Miqueu Karinne2
Leroux Frédéric R.2
Tuccio Beátrice2
Panossian Armen2
André-Barrès Christiane2
Jean-François Lohier2
Vimont Alexandre2
Salles Fabrice2
Guillot Regis2
Guillot Régis2
Serre C.2
Prieto Alexis2
Daturi Marco2
Jelier Benson2
Taponard Alexis2
Dell’amico Luca2
A. Ramsahye Naseem1
Babichenko Liudmila N.1
Bahlaouan Zineb1
Baldon Simone1
Barthélémy Lucas1
Belkadi Mohamed1
Bennai Nedjwa1
Benyettou Farah1
Berbezier Isabelle1
Bernard Monique1
Bernardelli Patrick1
Bertin Luc1
Besrour Hend1
Blanchard-Desce M.1
Bornette Gudrun1
Bortolato Tommaso1
Bourdreux F.1
Bourne Aaron1
Bresch Didier1
Buncel Erwin1
Cadoret Frederic1
Camerel Franck1
Cardin Philippe1
Carreira Erick1
Certal Victor1
Chefdeville Emmanuel1
Chevreau Hubert1
Clift S.1
Comon-Lundh Hubert1
Constant-Urban Céline1
Corlay Hervé1
Courtes Philippe1
Damond Aurélie1
Daniel Marion1
De-Zordo Banliat Arnaud1
Dell'Amico Luca1
Desmarchelier Alaric1
Devic Thomas1
Diebolt Claude1
Dronkina Maya I1
Dutson Claire L.1
Egidio Rodrigues Alirio1
El-Ahmad Youssef1
Escande Aude1
Fabien Laurence1
Fabry Paul1
Fakih Yara1
Fensterbank Hélène1
Filatov Andrey1
Fize Jennifer1
Fouquet Eric1
Férey Gérard1
G. Yot Pascal1
Garcia-Marquez Alfonso1
Gaudin Yves1
Ghiazza Clément1
Guidotti Jérôme1
Guilot Régis1
Haghiri-Gosnet Anne Marie1
Hapiot Philippe1
Hathout Nabil1
Henault Killian1
Hijazi Akram1
Hoffmann Philippe1
Holdsworth Peter1
Hong Ren1
Horcajada Patricia1
Hédouin Matthieu1
Ibrahim Nada1
José A.1
Kalinin Ihor1
Kemmegne-Mbouguen Justin Claude1
Kesküla Carmen1
Khuong Trung Thuy1
Klein Pierre-André1
Kolodziej Emilie1
Kumanetska Liliia1
Latroche Michel1
Laurent Guy1
Lavalley Jean-Claude1
Lavrard Hubert1
Le Droumaguet C.1
Le Du Eliott1
Le Thanh Nghi1
Leblanc Catherine1
Leclerc Nathalie1
Lipetskij Volidimir O.1
Lipetskij Volodimir1
Macé Y.1
Magder Karine1
Magnier-Bouvier Caroline1
Majira Amel A.1
Marechal Eric1
Marrot Jérôme C.1
Mazaj Matjaz1
Mendes Patricia1
Messara Amélia1
Mongin O.1
Monmotton Sophie1
Motherwell William1
Moïse Joëlle1
Mérienne Claude1
Ngi Samuel Inack1
Auteurs de la structure
Revues
- European Journal of Organic Chemistry21
- Chemistry - A European Journal11
- Organic Letters10
- Angewandte Chemie International Edition9
- Tetrahedron Letters9
- Tetrahedron7
- Synthesis: Journal of Synthetic Organic Chemistry5
- Advanced Synthesis and Catalysis5
- Journal of Fluorine Chemistry4
- Molecules4
- SYNLETT4
- Chemical Communications3
- Dalton Transactions3
- Beilstein Journal of Organic Chemistry3
- Journal of Organic Chemistry3
- Journal of the American Chemical Society3
- Organic Process Research and Development2
- L'Actualité Chimique2
- Chemical Science2
- ChemSusChem1
- Bioorganic and Medicinal Chemistry1
- Chemistry of Materials1
- CHIMIA1
- Collection of Czechoslovak Chemical Communications1
- Comptes Rendus. Chimie1
- Chemical Record1
- Helvetica Chimica Acta1
- Journal of Medicinal Chemistry1
- Magnetic Resonance in Chemistry1
- New Journal of Chemistry1
- Steroids1
- Advanced Functional Materials1
Année de production
Institutions
Laboratoires
Départements
Équipes de recherche
135 documents
Articles dans une revue122 document
- Gabriel Goujon, Marina Briand, Nathalie Leclerc, Bruce Pégot, Guillaume Dagousset, et al.. Multigram-Scale Synthesis and Study of Reactivity of Two Difluoromethylating Reagents Based on Sulfoximine Skeletons. Organic Process Research and Development, 2025, ⟨10.1021/acs.oprd.5c00148⟩. ⟨hal-05143166⟩
- Simone Baldon, Julien Paut, Elsa Anselmi, Guillaume Dagousset, Béatrice Tuccio, et al.. Radical photochemical difluorosulfoximination of alkenes and propellanes. Chemical Science, In press, ⟨10.1039/d5sc01068c⟩. ⟨hal-05019725⟩
- Augustin Nouaille, Francesco Terzani, Yara Fakih, Jérôme Hannedouche, Emmanuel Magnier, et al.. Metal‐Free Multicatalytic Decarbonylation of Aldehydes Driven by Light. Angewandte Chemie International Edition, 2025, 64 (15), pp.e202424459. ⟨10.1002/anie.202424459⟩. ⟨hal-04949214⟩
- Camille Banoun, Flavien Bourdreux, Emmanuel Magnier, Guillaume Dagousset. Site‐Selective γ‐Trihalomethylation and γ‐Dihalomethylidenation of Silyl Dienol Ethers under Organophotoredox Catalysis. Chemistry - A European Journal, 2024, ⟨10.1002/chem.202403598⟩. ⟨hal-04833542⟩
- Elsa Anselmi, Bénédicte Montigny, Märt Lõkov, Carmen Kesküla, Jan Erik Soosaar, et al.. Focus on Physico‐Chemical Properties of Sulfoximines: Acidity, Basicity and Lipophilicity. Chemistry - A European Journal, 2024, 31 (1), pp.e202402329. ⟨10.1002/chem.202402329⟩. ⟨hal-04814363⟩
- Peng Wu, Gabriel Goujon, Shulei Pan, Béatrice Tuccio, Bruce Pégot, et al.. Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis. Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202412418⟩. ⟨hal-04785277⟩
- Yang Li, Guillaume Dagousset, Emmanuel Magnier, Bruce Pégot. From perfluoroalkyl aryl sulfoxides to ortho thioethers. Beilstein Journal of Organic Chemistry, 2024, 20, pp.2108-2113. ⟨10.3762/bjoc.20.181⟩. ⟨hal-04689107⟩
- Julien Paut, Simone Baldon, Elsa Anselmi, Luca Dell'Amico, Guillaume Dagousset, et al.. Photocatalytic α‐Difluoroalkoxyketones Synthesis via Radical Intermolecular Alkoxylation of Difluoroenol Silyl Ethers. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400510⟩. ⟨hal-04680319⟩
- Marina Briand, Emmanuel Magnier, Elsa Anselmi, Guillaume Dagousset. Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400462⟩. ⟨hal-04665645⟩
- Camille Banoun, Killian Henault, Emmanuel Magnier, Guillaume Dagousset. One‐Pot Regioselective γ‐Trifluoromethylthiolation and γ‐Methylthiolation of Enals. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202400119⟩. ⟨hal-04533535⟩
- Sara Cuadros, Julien Paut, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier, et al.. Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres. Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202317333⟩. ⟨hal-04451019⟩
- Yang Li, Marina Briand, Karinne Miqueu, Elsa Anselmi, Emmanuel Magnier, et al.. Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals. Chemistry - A European Journal, 2024, 30 (10), pp.e202303545. ⟨10.1002/chem.202303545⟩. ⟨hal-04404468⟩
- Thibaut Duhail, Samir Messaoudi, Guillaume Dagousset, Jérôme Marrot, Christiane André-Barrès, et al.. Benzodithiazoles‐Sulfoximines: Preparation, Properties and Reactivities as Radical Perfluoroalkylating Agents. Advanced Synthesis and Catalysis, 2023, 365 (14), pp.2392-2399. ⟨10.1002/adsc.202300553⟩. ⟨hal-04161292⟩
- Marina Briand, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier. The revival of Enantioselective Perfluoroalkylation – Update of New Synthetic Approaches from 2015–2022. Chemical Record, 2023, ⟨10.1002/tcr.202300114⟩. ⟨hal-04125052⟩
- Arnaud de Zordo-Banliat, Kevin Grollier, Nicolas Vanthuyne, Sébastien Floquet, Thierry Billard, et al.. Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties. Angewandte Chemie International Edition, 2023, 62 (12), ⟨10.1002/anie.202300951⟩. ⟨hal-04046563⟩
- Camille Banoun, Emmanuel Magnier, Guillaume Dagousset. Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C-O Bond Formation. SYNLETT, 2023, ⟨10.1055/a-2131-4126⟩. ⟨hal-04231477⟩
- Matthieu Hédouin, Anne‐laure Barthelemy, Nicolas Vanthuyne, Hend Besrour, Jacques Maddaluno, et al.. NMR and DFT Studies with a Doubly Labelled 15 N/ 6 Li S ‐Trifluoromethyl Sulfoximine Reveal Why a Directed ortho ‐Lithiation Requires an Excess of n ‐BuLi. Angewandte Chemie International Edition, 2023, 62 (5), pp.e202214106. ⟨10.1002/anie.202214106⟩. ⟨hal-03912827⟩
- Thibaut Duhail, Jorna Kalim, Jérôme Marrot, Bruce Pégot, Emmanuel Magnier, et al.. Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202300963⟩. ⟨hal-04316672⟩
- Emmanuel Magnier, Guillaume Dagousset. Fluorine and chalcogen atoms: An association of benefactors. Tetrahedron, 2022, 113, pp.132754. ⟨10.1016/j.tet.2022.132754⟩. ⟨hal-03687520⟩
- Thibaut Duhail, Mingxiang Zhu, Coralie Rombault, Guillaume Dagousset, Samir Messaoudi, et al.. Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202200173⟩. ⟨hal-03668549⟩
- Arnaud de Zordo-Banliat, Kevin Grollier, Jordan Vigier, Erwann Jeanneau, Guillaume Dagousset, et al.. Vinylic Trifluoromethylselenolation via Pd‐Catalyzed C−H Activation. Chemistry - A European Journal, In press, ⟨10.1002/chem.202202299⟩. ⟨hal-03784203⟩
- Marina Briand, Linh Thai, Flavien Bourdreux, Nicolas Vanthuyne, Xavier Moreau, et al.. Remote Radical Trifluoromethylation: A Unified Approach to the Selective Synthesis of γ-Trifluoromethyl α,β-Unsaturated Carbonyl Compounds. Organic Letters, 2022, 24 (51), pp.9375-9380. ⟨10.1021/acs.orglett.2c03676⟩. ⟨hal-03936896⟩
- Arnaud De-Zordo Banliat, Kévin Grollier, Aurélie Damond, Thierry Billard, Guillaume Dagousset, et al.. Solvent free nucleophilic selenocyanation with [bmim][SeCN]. Direct access to perfluoroalkylselenide compounds. Tetrahedron, 2021, 101, pp.132507. ⟨10.1016/j.tet.2021.132507⟩. ⟨hal-03834344⟩
- Kevin Grollier, Emmanuel Chefdeville, Arnaud de Zordo-Banliat, Bruce Pegot, Guillaume Dagousset, et al.. Fe-mediated nucleophilic trifluoromethylselenolation of activated alkyl bromides via umpolung reactivity of trifluoromethyl tolueneselenosulfinate. Tetrahedron, 2021, 100, pp.132498. ⟨10.1016/j.tet.2021.132498⟩. ⟨hal-03834329⟩
- Thibaut Duhail, Tommaso Bortolato, Javier Mateos, Elsa Anselmi, Benson Jelier, et al.. Radical α-Trifluoromethoxylation of Ketones under Batch and Flow Conditions by Means of Organic Photoredox Catalysis. Organic Letters, 2021, 23 (18), pp.7088-7093. ⟨10.1021/acs.orglett.1c02494⟩. ⟨hal-03380290⟩
- Yohan Martinetto, Bruce Pégot, Catherine Roch, Mohamed Haouas, Betty Cottyn Boitte, et al.. A decatungstate-based Ionic liquid exhibiting very low dielectric constant suitable for acting as solvent and catalyst for oxidation of organic substrates. New Journal of Chemistry, 2021, 45 (22), pp.9751-9755. ⟨10.1039/D1NJ01214B⟩. ⟨hal-03231821⟩
- Yohan Martinetto, Salomé Basset, Bruce Pégot, Catherine Roch-Marchal, Franck Camerel, et al.. Synthesis, Physical Properties and Application of a Series of New Polyoxometalate-Based Ionic Liquids. Molecules, 2021, 26 (2), ⟨10.3390/molecules26020496⟩. ⟨hal-03120947⟩
- Kevin Grollier, Arnaud de Zordo‐banliat, Flavien Bourdreux, Bruce Pegot, Guillaume Dagousset, et al.. (Trifluoromethylselenyl)methylchalcogenyl as emerging fluorinated groups: synthesis under photoredox catalysis and determination of the lipophilicity. Chemistry - A European Journal, 2021, 27 (19), pp.6028-6033. ⟨10.1002/chem.202100053⟩. ⟨hal-03407531⟩
- Camille Banoun, Flavien Bourdreux, Emmanuel Magnier, Guillaume Dagousset. Intermolecular C-O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds. Organic Letters, 2021, 23 (22), pp.8926-8930. ⟨10.1021/acs.orglett.1c03444⟩. ⟨hal-03487851⟩
- Eliott Le Du, Thibaut Duhail, Matthew Wodrich, Rosario Scopelliti, Farzaneh Fadaei‐tirani, et al.. Structure and Reactivity of N‐Heterocyclic Alkynyl Hypervalent Iodine Reagents. Chemistry - A European Journal, 2021, 27 (42), ⟨10.1002/chem.202101475⟩. ⟨hal-03265356⟩
- Amélia Messara, Nicolas Vanthuyne, Patrick Diter, Mourad Elhabiri, Armen Panossian, et al.. Aryl Fluoroalkyl Sulfoxides: Optical Stability and p K a Measurement. European Journal of Organic Chemistry, 2021, 2021 (36), ⟨10.1002/ejoc.202100816⟩. ⟨hal-03319682⟩
- Kevin Grollier, Alexis Taponard, Arnaud de Zordo-Banliat, Emmanuel Magnier, Thierry Billard. Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate. Beilstein Journal of Organic Chemistry, 2020, 16, pp.3032 - 3037. ⟨10.3762/bjoc.16.252⟩. ⟨hal-03097741⟩
- Sébastien Bouvet, Bruce Pégot, Stéphane Sengmany, Erwan Le Gall, Eric Léonel, et al.. Controlled decomposition of SF6 by electrochemical reduction. Beilstein Journal of Organic Chemistry, 2020, 16, pp.2948 - 2953. ⟨10.3762/bjoc.16.244⟩. ⟨hal-03097747⟩
- Jorna Kalim, Thibaut Duhail, Ewa Pietrasiak, Elsa Anselmi, Emmanuel Magnier, et al.. Direct Trifluoromethylation of Alcohols Using a Hypervalent Iodosulfoximine Reagent. Chemistry - A European Journal, 2020, ⟨10.1002/chem.202005104⟩. ⟨hal-03121267⟩
- Kevin Grollier, Alexis Taponard, Clément Ghiazza, Emmanuel Magnier, Thierry Billard. Environmentally Compatible Access to α‐Trifluoromethylseleno‐Enones. Helvetica Chimica Acta, 2020, 103 (11), ⟨10.1002/hlca.202000185⟩. ⟨hal-03033317⟩
- Anne‐laure Barthelemy, F. Bourdreux, Guillaume Dagousset, Emmanuel Magnier. Photoredox-Catalyzed Selective Synthesis of Allylic Perfluoroalkanes from Alkenes. Chemistry - A European Journal, 2020, 26 (45), pp.10213-10216. ⟨10.1002/chem.202002046⟩. ⟨hal-02992795⟩
- Simon Rössler, Benson Jelier, Emmanuel Magnier, Guillaume Dagousset, Erick Carreira, et al.. Pyridinium Salts as Redox‐Active Functional Group Transfer Reagents. Angewandte Chemie International Edition, 2020, 59 (24), pp.9264-9280. ⟨10.1002/anie.201911660⟩. ⟨hal-02992788⟩
- Anne-Laure Barthelemy, Victor Certal, Guillaume Dagousset, Elsa Anselmi, Luc Bertin, et al.. Optimization and Gram-Scale Preparation of S -Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF 3 Group. Organic Process Research and Development, 2020, 24 (5), pp.704-712. ⟨10.1021/acs.oprd.9b00403⟩. ⟨hal-03097860⟩
- Anne-Laure Barthelemy, Guillaume Dagousset, Emmanuel Magnier. Metal-Free Visible-Light-Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow. European Journal of Organic Chemistry, 2020, 2020 (10), pp.1429-1432. ⟨10.1002/ejoc.201901252⟩. ⟨hal-02992749⟩
- Arnaud de Zordo-Banliat, Lucas Barthélémy, Flavien Bourdreux, Béatrice N. Tuccio, Guillaume Dagousset, et al.. Visible-Light-Induced Metal-Free Trifluoromethylselenolation of Electron-Rich Heteroarenes Using the Nucleophilic Me4N][SeCF3] Reagent. European Journal of Organic Chemistry, 2020, 2020 (4), pp.506-509. ⟨10.1002/ejoc.201901793⟩. ⟨hal-02861697⟩
- Nedjwa Bennai, Nada Ibrahim, Jérôme C. Marrot, Mohamed Belkadi, Mouâd Alami, et al.. Synthesis of S-Trifluoromethyl S-Arylsulfoximine Thioglycosides through Pd-Catalyzed Migita Cross-Coupling. European Journal of Organic Chemistry, 2020, 2020 (31), pp.4972-4981. ⟨10.1002/ejoc.202000821⟩. ⟨hal-02938398⟩
- Jorna Kalim, Thibaut Duhail, Thanh-Nghi Le, Nicolas Vanthuyne, Elsa Anselmi, et al.. Merging hypervalent iodine and sulfoximine chemistry: a new electrophilic trifluoromethylation reagent. Chemical Science, 2019, 10 (45), pp.10516-10523. ⟨10.1039/c9sc04289j⟩. ⟨hal-02514618⟩
- Christiane André-Barrès, Jacques Lalevée, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier, et al.. Spin trapping : la chasse aux intermédiaires radicalaires. L'Actualité Chimique, 2019. ⟨hal-03011793⟩
- Guillaume Levitre, Guillaume Dagousset, Elsa Anselmi, Béatrice Tuccio, Emmanuel Magnier, et al.. Four-Component Photoredox-Mediated Azidoalkoxy-trifluoromethylation of Alkenes. Organic Letters, 2019, 21 (15), pp.6005-6010. ⟨10.1021/acs.orglett.9b02152⟩. ⟨hal-02347070⟩
- Anne-Laure Barthelemy, Béatrice Tuccio, Emmanuel Magnier, Guillaume Dagousset. Intermolecular Trapping of Alkoxyl Radicals with Alkenes: A New Route to Ether Synthesis. SYNLETT, 2019, 30 (13), pp.1489-1495. ⟨10.1055/s-0037-1611785⟩. ⟨hal-02347568⟩
- Mingxiang Zhu, Guillaume Dagousset, Mouad Alami, Emmanuel Magnier, Samir Messaoudi. Ni/Photoredox-Dual-Catalyzed Functionalization of 1-Thiosugars. Organic Letters, 2019, 21 (13), pp.5132-5137. ⟨10.1021/acs.orglett.9b01730⟩. ⟨hal-02396639⟩
- Pascal G. Yot, Mohammad Wahiduzzaman, Erik Elkaim, Pierre Fertey, Paul Fabry, et al.. Correction: Modulation of the mechanical energy storage performance of the MIL-47(V IV ) metal organic framework by ligand functionalization. Dalton Transactions, 2019, 48 (8), pp.2823-2823. ⟨10.1039/c9dt90029b⟩. ⟨hal-02333360⟩
- Anne-Laure Barthelemy, Elsa Anselmi, Thanh-Nghi Le, Giang Vo-Thanh, Régis Guillot, et al.. Divergent Synthesis of 1,2-Benzo[ e ]thiazine and Benzo[ d ]thiazole Analogues Containing a S -Trifluoromethyl Sulfoximine Group: Preparation and New Properties of the Adachi Reagent. Journal of Organic Chemistry, 2019, 84 (7), pp.4086-4094. ⟨10.1021/acs.joc.9b00079⟩. ⟨hal-02093608⟩
- Liubov Sokolenko, Raisa Orlova, Andrey Filatov, Yurii Yagupolskii, Emmanuel Magnier, et al.. General, Practical and Selective Oxidation Protocol for CF3S into CF3S(O) Group. Molecules, 2019, 24 (7), pp.1249. ⟨10.3390/molecules24071249⟩. ⟨hal-02358280⟩
- Alexis Prieto, Patrick Diter, Martial Toffano, Jérôme Hannedouche, Emmanuel Magnier. Photoredox‐Initiated 1,2‐Difunctionalization of Alkenes with N ‐Chloro S ‐Fluoroalkyl Sulfoximines. Advanced Synthesis and Catalysis, 2018, 361 (3), pp.436-440. ⟨10.1002/adsc.201801207⟩. ⟨hal-02358288⟩
- Anne-Laure Barthelemy, Emmanuel Magnier, Guillaume Dagousset. Direct Trifluoromethylthiolation Reactions Involving Radical Processes. Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50 (24), pp.4765-4776. ⟨10.1055/s-0037-1611278⟩. ⟨hal-02347500⟩
- Anne-Laure Barthelemy, Alexis Prieto, Patrick Diter, Jérôme Hannedouche, Martial Toffano, et al.. Facile Preparation of Vinyl S -Trifluoromethyl N H Aryl Sulfoximines. European Journal of Organic Chemistry, 2018, 2018 (27-28), pp.3764-3770. ⟨10.1002/ejoc.201800324⟩. ⟨hal-02358294⟩
- Anne-Laure Barthelemy, Emmanuel Magnier. Recent trends in perfluorinated sulfoximines. Comptes Rendus. Chimie, 2018, 21 (8), pp.711-722. ⟨10.1016/j.crci.2018.01.004⟩. ⟨hal-02358299⟩
- Slim Chaabouni, Jean-François Lohier, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. One-Pot Synthesis of Aryl- and Alkyl S -Perfluoroalkylated NH -Sulfoximines from Sulfides. Chemistry - A European Journal, 2018, 24 (64), pp.17006-17010. ⟨10.1002/chem.201805055⟩. ⟨hal-01926255⟩
- Marina Thierry, Amel A. Majira, Bruce Pegot, Laurent Cezard, Flavien Bourdreux, et al.. Imidazolium‐Based Ionic Liquids as Efficient Reagents for the C−O Bond Cleavage of Lignin. ChemSusChem, 2018, 11 (2), pp.439-448. ⟨10.1002/cssc.201701668⟩. ⟨hal-01817782⟩
- Anne-Laure Barthelemy, Beátrice Tuccio, Emmanuel Magnier, Guillaume Dagousset. Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti-Markovnikov Alkoxylation Reactions. Angewandte Chemie International Edition, 2018, 57 (42), pp.13790--13794. ⟨10.1002/anie.201806522⟩. ⟨hal-02091883⟩
- Taras M Sokolenko, Maya I Dronkina, Emmanuel Magnier, Lev M Yagupolskii, Yurii L Yagupolskii. Evaluation of Efficient and Practical Methods for the Preparation of Functionalized Aliphatic Trifluoromethyl Ethers. Molecules, 2017, 22 (5), pp.804. ⟨10.3390/molecules22050804⟩. ⟨hal-05121187⟩
- Liubov Sokolenko, Yurii Yagupolskii, Liliia Kumanetska, Jérôme Marrot, Emmanuel Magnier, et al.. CF 3 S(O) n -containing enaminones as precursors for the synthesis of pyrimidine-4(3 H )-ones. Tetrahedron Letters, 2017, 58 (13), pp.1308-1311. ⟨10.1016/j.tetlet.2017.02.046⟩. ⟨hal-05130991⟩
- Guillaume Dagousset, Cédric Simon, Elsa Anselmi, Béatrice Tuccio, Thierry Billard, et al.. Generation of the SCF3 radical by photoredox catalysis: Intra- and intermolecular carbotrifluoromethylthiolation of alkenes. Chemistry - A European Journal, 2017, 23 (18), pp.4282-4286. ⟨10.1002/chem.201700734⟩. ⟨hal-01606062⟩
- Elsa Anselmi, Zineb Bahlaouan, Samuel Inack Ngi, Jean Luc Parrain, Emmanuel Magnier, et al.. Selective carboxylate directed ortho functionalization in copper catalyzed reactions of polyiodo aromatics: A straightforward preparation of 5,7-diiodo-1H-isochromen-1-ones. European Journal of Organic Chemistry, 2017, 41, pp.6131-6136. ⟨10.1002/ejoc.201700859⟩. ⟨hal-02619447⟩
- Marion Daniel, Guillaume Dagousset, Patrick Diter, Pierre-André Klein, Beátrice Tuccio, et al.. Fluorinated sulfilimino iminiums: a versatile source of perfluoroalkyl radicals under photoredox catalysis. Angewandte Chemie International Edition, 2017, ⟨10.1002/anie.201700290⟩. ⟨hal-02113752⟩
- Elsa Anselmi, Cédric Simon, Jerome Marrot, Patrick Bernardelli, Laurent Schio, et al.. Ionic Liquids for Fast and Solvent-Free Nucleophilic Trifluoromethylthiolation of Alkyl Halides and Alcohols. European Journal of Organic Chemistry, 2017, 2017 (42), pp.6319-6326. ⟨10.1002/ejoc.201701222⟩. ⟨hal-02624958⟩
- Riadh Zriba, Alaric Desmarchelier, Frederic Cadoret, Sebastien Bouvet, Anne-Laure Barthelemy, et al.. Dichlorotrifluoromethoxyacetic acid: Preparation and reactivity. Molecules, 2017, 22 (6), pp.1-7. ⟨10.3390/molecules22060966⟩. ⟨hal-01606613⟩
- Etienne Schmitt, Sebastien Bouvet, Bruce Pegot, Armen Panossian, Jean-Pierre Vors, et al.. Fluoroalkyl Amino Reagents for the Introduction of the Fluoro(trifluoromethoxy)methyl Group onto Arenes and Heterocycles. Organic Letters, 2017, 19 (18), pp.4960-4963. ⟨10.1021/acs.orglett.7b02444⟩. ⟨hal-02105321⟩
- Thanh-Nghi Le, Patrick Diter, Bruce Pégot, Chloée Bournaud, Martial Toffano, et al.. S -Trifluoromethyl Sulfoximine as a Directing Group in Ortho -Lithiation Reaction toward Structural Complexity. Organic Letters, 2016, 18 (19), pp.5102-5105. ⟨10.1021/acs.orglett.6b02548⟩. ⟨hal-05130984⟩
- Lucie Jarrige, Aude Carboni, Guillaume Dagousset, Guillaume Levitre, Emmanuel Magnier, et al.. Photoredox-Catalyzed Three-Component Tandem Process: An Assembly of Complex Trifluoromethylated Phthalans and Isoindolines. Organic Letters, 2016, 18 (12), pp.2906-2909. ⟨10.1021/acs.orglett.6b01257⟩. ⟨hal-02347519⟩
- Elsa Anselmi, - Thanh Nghi Le, Sebastien Bouvet, Patrick Diter, Bruce Pegot, et al.. Synthesis of N-Alkenyl and N-Alkynyl S-Perfluoroalkylated Sulfoximines by Copper Catalysis. European Journal of Organic Chemistry, 2016, 25, pp.4423 - 4428. ⟨10.1002/ejoc.201600649⟩. ⟨hal-02631721⟩
- Thanh-Nghi Le, Patrick Diter, Bruce Pégot, Chloée Bournaud, Martial Toffano, et al.. Functionalized S-perfluorinated sulfoximines: Preparation and evaluation in catalytic processes. Journal of Fluorine Chemistry, 2015, 179, pp.179-187. ⟨10.1016/j.jfluchem.2015.06.020⟩. ⟨hal-05131389⟩
- Aude Carboni, Guillaume Dagousset, Emmanuel Magnier, Geraldine Masson. Three-Component Photoredox-Mediated Chloro-, Bromo-, or Iodotrifluoromethylation of Alkenes. Synthesis: Journal of Synthetic Organic Chemistry, 2015, 47 (16), pp.2439-2445. ⟨10.1055/s-0034-1378715⟩. ⟨hal-02347532⟩
- Bruce Pégot, Céline Urban, Aaron Bourne, Thanh Nghi Le, Sébastien Bouvet, et al.. Difluoromethyl and Chlorofluoromethyl Sulfoximines: Synthesis and Evaluation as Electrophilic Perfluoroalkylating Reagents. European Journal of Organic Chemistry, 2015, 2015 (14), pp.3069-3075. ⟨10.1002/ejoc.201500201⟩. ⟨hal-05131384⟩
- Sébastien Bouvet, Bruce Pégot, Patrick Diter, Jérôme Marrot, Emmanuel Magnier. Oxidative desulfurization–fluorination reaction promoted by [bdmim][F] for the synthesis of difluorinated methyl ethers. Tetrahedron Letters, 2015, 56 (13), pp.1682-1686. ⟨10.1016/j.tetlet.2015.02.034⟩. ⟨hal-05131378⟩
- Thierry Billard, Emmanuel Magnier, Jean-Pierre Vors. Le fluor en chimie organique : une montée en puissance (Fluorine in organic chemistry gaining momentum). L'Actualité Chimique, 2015, 393-394, pp.56-61. ⟨hal-01313987⟩
- Liubov V. Sokolenko, Yurii L. Yagupolskii, Yurii G. Vlasenko, Liudmila N. Babichenko, Volidimir O. Lipetskij, et al.. Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction. Tetrahedron Letters, 2015, 56 (10), pp.1259-1262. ⟨10.1016/j.tetlet.2015.01.136⟩. ⟨hal-01170057⟩
- Aude Carboni, Guillaume Dagousset, Emmanuel Magnier, Géraldine Masson. One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis.. Chemical Communications, 2014, 50 (91), pp.14197-14200. ⟨hal-01104322⟩
- Patricia Mendes, Patricia Horcajada, Sébastien Rives, Alirio Egidio Rodrigues, Thomas Devic, et al.. A Complete Separation of Hexane Isomers by a Functionalized Flexible Metal Organic Framework. Advanced Functional Materials, 2014, xx (xx), ⟨10.1002/adfm.201401974⟩. ⟨hal-01077066⟩
- Guillaume Dagousset, Aude Carboni, Emmanuel Magnier, Géraldine Masson. Photoredox-induced three-component azido- and aminotrifluoromethylation of alkenes.. Organic Letters, 2014, 16 (16), pp.4340-4343. ⟨10.1021/ol5021477⟩. ⟨hal-01065684⟩
- Thanh-Nghi Le, Emilie Kolodziej, Patrick Diter, Bruce Pégot, Chloée Bournaud, et al.. First Isolation of Enantiopure Perfluoroalkylated Sulfilimines and Sulfoximines. CHIMIA, 2014, 68 (6), pp.410. ⟨10.2533/chimia.2014.410⟩. ⟨hal-05121417⟩
- Aude Carboni, Guillaume Dagousset, Emmanuel Magnier, Géraldine Masson. Photoredox-induced three-component oxy-, amino-, and carbotrifluoromethylation of enecarbamates. Organic Letters, 2014, 16 (4), pp.1240-1243. ⟨10.1021/ol500374e⟩. ⟨hal-00966064⟩
- Patricia Horcajada, Hubert Chevreau, Daniela Heurtaux, Farah Benyettou, Fabrice Salles, et al.. Extended and functionalized porous iron( III ) tri- or dicarboxylates with MIL-100/101 topologies. Chemical Communications, 2014, 50, pp.6872--6874. ⟨10.1039/c4cc02175d⟩. ⟨hal-01064282⟩
- Sébastien Bouvet, Bruce Pégot, Jérome Marrot, Emmanuel Magnier. Solvent free nucleophilic introduction of fluorine with [bmim][F]. Tetrahedron Letters, 2014, 55 (4), pp.826 - 829. ⟨10.1016/j.tetlet.2013.12.020⟩. ⟨hal-05121420⟩
- Yohan Macé, Céline Constant-Urban, Sébastien Bouvet, Bruce Pégot, Chloée Bournaud, et al.. A Mild and Efficient Procedure for the N-Functionalization of S-Perfluoroalkylated Aryl Sulfoximines. Synthesis: Journal of Synthetic Organic Chemistry, 2013, 45 (11), pp.1505-1512. ⟨10.1055/s-0033-1338440⟩. ⟨hal-05131369⟩
- Akram Hijazi, Justin Claude Kemmegne-Mbouguen, Sébastien Floquet, Jérôme Marrot, Jennifer Fize, et al.. Tuning the electrocatalytic hydrogen evolution reaction promoted by [Mo2O2S2]-based molybdenum cycles in aqueous medium.. Dalton Transactions, 2013, 42 (14), pp.4848-58. ⟨10.1039/c2dt32447d⟩. ⟨hal-01069166⟩
- Naseem A. Ramsahye, Thuy Khuong Trung, Lorna Scott, Farid Nouar, Thomas Devic, et al.. Impact of the Flexible Character of MIL-88 Iron(III) Dicarboxylates on the Adsorption of n-Alkanes. Chemistry of Materials, 2013, 25 (3), pp.479-488. ⟨10.1021/cm303830b⟩. ⟨hal-04395576⟩
- Bruce Pégot, Céline Urban, Patrick Diter, Emmanuel Magnier. Perfluoroalkylated Bis(sulfilimine)s and Bis(sulfoximine)s by a Ritter‐Type Reaction. European Journal of Organic Chemistry, 2013, 2013 (34), pp.7800 - 7808. ⟨10.1002/ejoc.201301017⟩. ⟨hal-05121430⟩
- Bruce Pégot, Yohan Macé, Céline Urban, Patrick Diter, Jean-Claude Blazejewski, et al.. Ionic liquids as new media for electrophilic trifluoromethylation reactions. Journal of Fluorine Chemistry, 2012, 134, pp.156-159. ⟨10.1016/j.jfluchem.2011.03.004⟩. ⟨hal-05131355⟩
- Yohan Macé, Emmanuel Magnier. The New Age of Electrophilic Perfluoroalkylation Reactions. European Journal of Organic Chemistry, 2012, 2012 (13), pp.2479-2494. ⟨10.1002/ejoc.201101535⟩. ⟨hal-05123366⟩
- Cédric Rouxel, C. Le Droumaguet, Y. Macé, S. Clift, O. Mongin, et al.. Octupolar derivatives functionalized with superacceptor peripheral groups Synthesis and evaluation of the electron-withdrawing ability of potent unusual groups. Chemistry - A European Journal, 2012, 18 (39), pp.12487-12497. ⟨10.1002/chem.201103460⟩. ⟨hal-02296063⟩
- Yohan Macé, Bruce Pégot, Régis Guillot, Chloée Bournaud, Martial Toffano, et al.. Efficient copper-induced coupling between NH-fluoroalkylated sulfoximines and aryl iodides or bromides. Tetrahedron, 2011, 67 (39), pp.7575-7580. ⟨10.1016/j.tet.2011.07.060⟩. ⟨hal-05123370⟩
- Céline Urban, Frédéric Cadoret, Jean‐claude Blazejewski, Emmanuel Magnier. Sulfoximines as a Versatile Scaffold for Electrophilic Fluoroalkylating Reagents. European Journal of Organic Chemistry, 2011, 2011 (25), pp.4862-4867. ⟨10.1002/ejoc.201100503⟩. ⟨hal-05123372⟩
- Claudia Zlotea, Delphine Phanon, Matjaz Mazaj, Daniela Heurtaux, Vincent Guillerm, et al.. Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs. Dalton Transactions, 2011, 40 (18), pp.4879. ⟨10.1039/c1dt10115c⟩. ⟨hal-05123375⟩
- Patricia Horcajada, F. Salles, Thomas Devic, Guillaume Maurin, Alexandre Vimont, et al.. How linker's modification controls swelling properties of highly flexible iron(III) dicarboxylates MIL-88. Journal of the American Chemical Society, 2011, pp.17839. ⟨10.1021/ja206936e⟩. ⟨hal-00632455⟩
- Céline Urban, Yohan Macé, Frédéric Cadoret, Jean‐claude Blazejewski, Emmanuel Magnier. Divergent Preparation of Fluoroalkylated Sulfilimine and Sulfilimino Iminium Salts. Advanced Synthesis and Catalysis, 2010, 352 (16), pp.2805-2814. ⟨10.1002/adsc.201000494⟩. ⟨hal-05123379⟩
- Yohan Macé, Charlotte Pradet, Matthew Popkin, Jean-Claude Blazejewski, Emmanuel Magnier. Mechanistical insight into ‘electrophilic’ trifluoromethylation with S-(trifluoromethyl)dibenzothiophenium salts. Tetrahedron Letters, 2010, 51 (41), pp.5388-5391. ⟨10.1016/j.tetlet.2010.07.154⟩. ⟨hal-05123389⟩
- Yohan Macé, Jean‐claude Blazejewski, Charlotte Pradet, Emmanuel Magnier. Self‐Immolative Reduction of Trifluoromethyl Sulfoxides Promoted by Trifluoromethanesulfonic Anhydride. European Journal of Organic Chemistry, 2010, 2010 (30), pp.5772-5776. ⟨10.1002/ejoc.201001069⟩. ⟨hal-05123388⟩
- Thomas Devic, Patricia Horcajada, C. Serre, Fabrice Salles, Guillaume Maurin, et al.. Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host-Guest Interactions. Journal of the American Chemical Society, 2010, 132 (3), pp.1127-1136. ⟨10.1021/ja9092715⟩. ⟨hal-00474406⟩
- Yohan Macé, Céline Urban, Charlotte Pradet, Jean‐claude Blazejewski, Emmanuel Magnier. Aromatic and Benzylic C–H Bond Functionalization Upon Reaction between Nitriles and Perfluoroalkyl Sulfoxides. European Journal of Organic Chemistry, 2009, 2009 (31), pp.5313-5316. ⟨10.1002/ejoc.200900873⟩. ⟨hal-05123395⟩
- Yohan Macé, Céline Urban, Charlotte Pradet, Jérôme Marrot, Jean‐claude Blazejewski, et al.. Sulfilimines and Sulfoximines by Reaction of Nitriles with Perfluoroalkyl Sulfoxides. European Journal of Organic Chemistry, 2009, 2009 (19), pp.3150-3153. ⟨10.1002/ejoc.200900410⟩. ⟨hal-05131344⟩
- Riadh Zriba, Emmanuel Magnier, Jean-Claude Blazejewski. Preparation and Reactivity of some New Keto- and Styrene-Based Trifluoromethoxylated Synthons. SYNLETT, 2009, 2009 (07), pp.1131-1135. ⟨10.1055/s-0028-1088155⟩. ⟨hal-05123404⟩
- Yohan Macé, Benoit Raymondeau, Charlotte Pradet, Jean‐claude Blazejewski, Emmanuel Magnier. Benchmark and Solvent‐Free Preparation of Sulfonium Salt Based Electrophilic Trifluoromethylating Reagents. European Journal of Organic Chemistry, 2009, 2009 (9), pp.1390-1397. ⟨10.1002/ejoc.200801222⟩. ⟨hal-05123406⟩
- Vangelis Agouridas, Emmanuel Magnier, Jean-Claude Blazejewski, Ioanna Laïos, Anny Cleeren, et al.. Effect of Fluorination on the Pharmacological Profile of 11β Isomers of Fulvestrant in Breast Carcinoma Cells. Journal of Medicinal Chemistry, 2009, 52 (3), pp.883-887. ⟨10.1021/jm801154q⟩. ⟨hal-05123408⟩
- Emmanuel Magnier, Patrick Diter, Jean-Claude Blazejewski. The trifluoromethoxy group as a fluorine twin in the Diels–Alder reactions of halogenated quinones. Tetrahedron Letters, 2008, 49 (31), pp.4575-4578. ⟨10.1016/j.tetlet.2008.05.104⟩. ⟨hal-05123410⟩
- Vangelis Agouridas, Jean-Claude Blazejewski, Anny Cleeren, Ioanna Laïos, Guy Leclercq, et al.. Fluorous tolerance of the estrogen receptor alpha as probed by 11-polyfluoroalkylestradiol derivatives. Steroids, 2008, 73 (3), pp.320-327. ⟨10.1016/j.steroids.2007.11.002⟩. ⟨hal-05131336⟩
- Augustin de Castries, Aude Escande, Hélène Fensterbank, Emmanuel Magnier, Jérôme Marrot, et al.. Synthesis of N-tetrasubstituted cyclam derivatives appended with sulfonyl or sulfinyl groups via aza-Michael addition. Tetrahedron, 2007, 63 (41), pp.10330-10336. ⟨10.1016/j.tet.2007.07.067⟩. ⟨hal-05123411⟩
- Patrick Diter, Emmanuel Magnier, Jean-Claude Blazejewski. Evaluation of Zard trifluoromethylketone synthesis for the preparation of potential bifunctional fluorinated synthons. Journal of Fluorine Chemistry, 2007, 128 (10), pp.1235-1240. ⟨10.1016/j.jfluchem.2007.05.002⟩. ⟨hal-05123413⟩
- Caroline Magnier-Bouvier, Jean-Claude Blazejewski, Chantal Larpent, Emmanuel Magnier. Selective Michael additions of primary and secondary amines to perfluoroalkylated sulfoxides and sulfones as a tool for fluorous tagging. Tetrahedron Letters, 2006, 47 (51), pp.9121-9124. ⟨10.1016/j.tetlet.2006.10.077⟩. ⟨hal-05123422⟩
- Vangelis Agouridas, Anny Cleeren, Elyane Kizilian, Emmanuel Magnier, Jean-Claude Blazejewski, et al.. Loss of antagonistic activity of tamoxifen by replacement of one N-methyl of its side chain by fluorinated residues. Bioorganic and Medicinal Chemistry, 2006, 14 (22), pp.7531-7538. ⟨10.1016/j.bmc.2006.07.012⟩. ⟨hal-05123424⟩
- Marc Tordeux, Emmanuel Magnier, Jean-Claude Blazejewski, Claude Wakselman. Straightforward One-Pot Synthesis of Trifluoromethyl Sulfonium Salts. Angewandte Chemie International Edition, 2006, 45, pp.1279. ⟨10.1002/anie.200503776⟩. ⟨hal-00094238⟩
- Augustin de Castries, Emmanuel Magnier, Sophie Monmotton, Hélène Fensterbank, Chantal Larpent. An Expedient Synthesis of Perfluorinated Tetraazamacrocycles: New Ligands for Copper-Catalyzed Oxidation under Fluorous Biphasic Conditions. European Journal of Organic Chemistry, 2006, 20, pp.4685. ⟨10.1002/ejoc.200600523⟩. ⟨hal-00103882⟩
- Vangelis Agouridas, Jean-Claude Blazejewski, Emmanuel Magnier, Matthew Popkin. Synthesis of 11β-Perfluorohexylestradiol. Journal of Organic Chemistry, 2005, 70 (22), pp.8907-8912. ⟨10.1021/jo051424k⟩. ⟨hal-05123426⟩
- François Terrier, Emmanuel Magnier, Elyane Kizilian, Claude Wakselman, Erwin Buncel. Superacidifiers: Assessing the Activation and the Mode of Charge Transmission of the Extraordinary Electron-Withdrawing SO 2 CF 3 and S(O)(NSO 2 CF 3 )CF 3 Substituents in Carbanion Stabilization. Journal of the American Chemical Society, 2005, 127 (15), pp.5563-5571. ⟨10.1021/ja0436291⟩. ⟨hal-05123430⟩
- Joëlle Moïse, Régis Goumont, Emmanuel Magnier, Claude Wakselman. Synthesis of Fluoroalkyl Vinyl Sulfoxides and their Use in Diels-Alder Reactions. Synthesis: Journal of Synthetic Organic Chemistry, 2004, 2004 (14), pp.2297-2302. ⟨10.1055/s-2004-831201⟩. ⟨hal-05123433⟩
- Marc Tordeux, Emmanuel Magnier, Jérôme Guidotti, Patrick Diter, Claude Wakselman. 29/28, 30/28Silicon, 34/32sulfur and 80/77selenium isotope-induced fluorine chemical shifts through two bonds. Magnetic Resonance in Chemistry, 2004, 42, pp.700. ⟨10.1002/mrc.1422⟩. ⟨hal-00093911⟩
- Régis Goumont, Emmanuel Magnier, Elyane Kizilian, François Terrier. Acidity Inversions of α-NO 2 and α-SO 2 CF 3 Activated Carbon Acids as a Result of Contrasting Solvent Effects on Transfer from Water to Dimethyl Sulfoxide Solutions. Journal of Organic Chemistry, 2003, 68 (17), pp.6566-6570. ⟨10.1021/jo034244o⟩. ⟨hal-05123436⟩
- Marc Tordeux, Emmanuel Magnier, Régis Goumont, Karine Magder, Claude Wakselman. Perfluoroalkylation of 2-mercaptoethanol as a key step for a new synthesis of perfluoroalkyl vinyl sulfides, sulfoxides and sulfones. Journal of Fluorine Chemistry, 2003, 124, pp.55. ⟨10.1016/S0022-1139(03)00170-2⟩. ⟨hal-00094395⟩
- Emmanuel Magnier, Claude Wakselman. The Preparation of Aliphatic Fluorinated Sulfoximines. Synthesis: Journal of Synthetic Organic Chemistry, 2003, 2003 (04), pp.0565-0569. ⟨10.1055/s-2003-37651⟩. ⟨hal-05123440⟩
- Emmanuel Magnier, Claude Wakselman. A Mild and Practical Preparation of Trifluoromethaneselenenyl Chloride. Collection of Czechoslovak Chemical Communications, 2002, 67 (9), pp.1262-1266. ⟨10.1135/cccc20021262⟩. ⟨hal-05131033⟩
- Emmanuel Magnier, Erica Vit, Claude Wakselman. A Convenient Access to Perfluoroalkyl Selenoethers and Selenyl Chlorides. SYNLETT, 2001, 2001 (08), pp.1260-1262. ⟨10.1055/s-2001-16050⟩. ⟨hal-05123444⟩
- Hervé Corlay, Eric Fouquet, Emmanuel Magnier, William Motherwell. Observations on the versatility of methylenecyclopropanes as olefinic components in the intramolecular Pauson–Khand reaction. Chemical Communications, 1999, 2, pp.183-184. ⟨10.1039/A807333C⟩. ⟨hal-05123446⟩
- Emmanuel Magnier, Yves Langlois. Manzamine alkaloids, syntheses and synthetic approaches. Tetrahedron, 1998, 54 (23), pp.6201-IN2. ⟨10.1016/S0040-4020(98)00357-3⟩. ⟨hal-05123447⟩
- Thierry Vidal, Emmanuel Magnier, Yves Langlois. Formal synthesis of Manzamine C via a sila-Cope elimination. Tetrahedron, 1998, 54 (22), pp.5959-5966. ⟨10.1016/S0040-4020(98)00270-1⟩. ⟨hal-05123448⟩
- Emmanuel Magnier, Yves Langlois. Zincke-bradsher convergent strategy for the synthesis of the ABE tricyclic core of Manzamine A. Tetrahedron Letters, 1998, 39 (8), pp.837-840. ⟨10.1016/S0040-4039(97)10744-4⟩. ⟨hal-05123449⟩
- Emmanuel Magnier, Claude Mérienne, Yves Langlois. Stereoselective synthesis of the tricyclic core of manzamine a: The bradsher cycloaddition route. Tetrahedron Letters, 1995, 36 (52), pp.9475-9478. ⟨10.1016/0040-4039(95)02071-3⟩. ⟨hal-05123452⟩
Communications dans un congrès8 document
- Emmanuel Magnier. Recent developments in the preparation of molecules merging fluorine and chalcogen atoms. 23TH International Symposium of Fluorine Chemistry, Jul 2023, Québec (CA), Canada. ⟨hal-04373929⟩
- Emmanuel Magnier. S-perfluoroalkyl sulfoximines: from synthesis to reactivity on photoredox catalysis. France-Japan joint symposium on organofluorine chemistry, Nov 2019, Strasbourg, France. ⟨hal-04373926⟩
- Emmanuel Magnier. S-perfluoroalkyl sulfoximines: from synthesis to reactivity on photoredox catalysis. Organic chemistry in Paris, Conférences de l’institut de chimie du Collège de France, Sep 2019, Paris, France. ⟨hal-04373922⟩
- Emmanuel Magnier. Photoredox catalysis: a powerful tool to prepare perfluoroalkylated and trifluoromethylthiolated molecules. 10ème Conférence Internationale de Chimie Toulouse-Kiev (ICTK - 10), Jun 2019, Toulouse, France. ⟨hal-04401739⟩
- Emmanuel Magnier. S-Perfluoroalkyl sulfoximines: preparation and use as source of radicals under photoredox catalysis. Progress in Organofluorine Chemistry, Le studium conference, Oct 2018, Orléans, France. ⟨hal-04373918⟩
- Slim Chaabouni, Lohier Jean-François, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. New and general access to S-perfluoroalkyl NH sulfoximines. 22nd International Symposium on fluorine chemistry, Jul 2018, Oxford, United Kingdom. ⟨hal-01828289⟩
- Emmanuel Magnier. New and general access to S-perfluoroalkyl NH sulfoximines. 22st International Symposium on Fluorine Chemistry (22stISFC), Jul 2018, Oxford, United Kingdom. ⟨hal-04373912⟩
- Slim Chaabouni, Lohier Jean-François, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. New and general access to S-perfluoroalkyl NH sulfoximines. Journée scientifique du labex CHARM3AT, Jun 2018, Cachan, France. ⟨hal-01828299⟩
Poster de conférence2 document
- Emmanuel Magnier. Hypervalent Iodosulfoximines synthesis - An access to new perfluoroalkylating reagents. 55th Bürgenstock Conference, May 2022, Brunnen, Switzerland. . ⟨hal-04400529⟩
- Emmanuel Magnier. S-perfluoroalkylated sulfoximines : synthesis and properties. 54th Bürgenstock Conference, May 2019, Brunnen, Switzerland. ⟨hal-04422847⟩
Chapitres d'ouvrage1 document
- Emmanuel Magnier. Construction of S-RF Sulfilimines and S-RF Sulfoximines. Emerging Fluorinated Motifs - Synthesis, Properties and Applications, 2020. ⟨hal-04386034⟩
Autres publications1 document
- Anne‐laure Barthelemy, Guillaume Dagousset, Emmanuel Magnier. Cover Feature: Metal‐Free Visible‐Light‐Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow (Eur. J. Org. Chem. 10/2020). 2019, pp.1190-1190. ⟨10.1002/ejoc.201901800⟩. ⟨hal-04417657⟩
Pré-publications, Documents de travail1 document
- Olivier Coutard, Pierre-Olivier Amblard, Claude Amra, Brigitte Bacroix, Pascal Barone, et al.. CPCN - BILAN DE MANDATURE 2016 – 2021. 2021. ⟨hal-03413289v2⟩
Diplômes
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- Habilitation à Diriger des Recherches de l’Université de Versailles 28 nov 2007
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- Doctorat de Chimie Organique de l’Université Paris XI (Orsay) 29 oct 1997
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- • Directeur de thèse : Pr. Yves LANGLOIS
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- • Sujet : Nouvelle approche synthétique des alcaloïdes de type manzamine
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- • Financement : Ministère de la Recherche et de L’Enseignement Supérieur
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- D.E.A. de Chimie Organique de l’Université Paris XI (Orsay) juin 1993
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- • Responsable Scientifique : Pr. Yves LANGLOIS
- • Sujet : Nouvelle approche synthétique des alcaloïdes de type manzamine
Fonctions de recherche
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- Directeur de Recherche au CNRS à l’Université de Versailles Saint-Quentin depuis oct 2012
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- Chargé de Recherche au CNRS à l’Université de Versailles Saint-Quentin oct 1999-2012
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- Attaché temporaire d’enseignement et de recherche 1998-1999
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- • Responsables scientifiques : Prs. Henri B. KAGAN et Jean-Claude FIAUD
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- • Sujet : Synthèse de diphosphines optiquement actives
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- Stage postdoctoral à l’University College London 1997-1998
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- • Responsable scientifique : Pr. William B. MOTHERWELL
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- • Sujet : Réaction de Pauson-Khand intramoléculaire sur des systèmes cyclopropaniques.
- • Financement : Bourse Lavoisier du Ministère des Affaires Etrangères.