Guillaume DAGOUSSET 

Chargé de Recherche 



FLUOPEPIT, Permanent


guillaume.dagousset@cnrs.fr


018000

HM1- 1er étage - 1509


https://orcid.org/0000-0001-8720-3828
























61 documents







Articles dans une revue53 document




    

  • Gabriel Goujon, Marina Briand, Nathalie Leclerc, Bruce Pégot, Guillaume Dagousset, et al.. Multigram-Scale Synthesis and Study of Reactivity of Two Difluoromethylating Reagents Based on Sulfoximine Skeletons. Organic Process Research and Development, 2025, ⟨10.1021/acs.oprd.5c00148⟩. ⟨hal-05143166⟩
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  • Simone Baldon, Julien Paut, Elsa Anselmi, Guillaume Dagousset, Béatrice Tuccio, et al.. Radical photochemical difluorosulfoximination of alkenes and propellanes. Chemical Science, In press, ⟨10.1039/d5sc01068c⟩. ⟨hal-05019725⟩
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  • Augustin Nouaille, Francesco Terzani, Yara Fakih, Jérôme Hannedouche, Emmanuel Magnier, et al.. Metal‐Free Multicatalytic Decarbonylation of Aldehydes Driven by Light. Angewandte Chemie International Edition, 2025, 64 (15), pp.e202424459. ⟨10.1002/anie.202424459⟩. ⟨hal-04949214⟩
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  • Camille Banoun, Flavien Bourdreux, Emmanuel Magnier, Guillaume Dagousset. Site‐Selective γ‐Trihalomethylation and γ‐Dihalomethylidenation of Silyl Dienol Ethers under Organophotoredox Catalysis. Chemistry - A European Journal, 2024, ⟨10.1002/chem.202403598⟩. ⟨hal-04833542⟩
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  • Peng Wu, Gabriel Goujon, Shulei Pan, Béatrice Tuccio, Bruce Pégot, et al.. Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis. Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202412418⟩. ⟨hal-04785277⟩
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  • Yang Li, Guillaume Dagousset, Emmanuel Magnier, Bruce Pégot. From perfluoroalkyl aryl sulfoxides to ortho thioethers. Beilstein Journal of Organic Chemistry, 2024, 20, pp.2108-2113. ⟨10.3762/bjoc.20.181⟩. ⟨hal-04689107⟩
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  • Julien Paut, Simone Baldon, Elsa Anselmi, Luca Dell'Amico, Guillaume Dagousset, et al.. Photocatalytic α‐Difluoroalkoxyketones Synthesis via Radical Intermolecular Alkoxylation of Difluoroenol Silyl Ethers. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400510⟩. ⟨hal-04680319⟩
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  • Marina Briand, Emmanuel Magnier, Elsa Anselmi, Guillaume Dagousset. Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400462⟩. ⟨hal-04665645⟩
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  • Camille Banoun, Killian Henault, Emmanuel Magnier, Guillaume Dagousset. One‐Pot Regioselective γ‐Trifluoromethylthiolation and γ‐Methylthiolation of Enals. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202400119⟩. ⟨hal-04533535⟩
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  • Sara Cuadros, Julien Paut, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier, et al.. Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres. Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202317333⟩. ⟨hal-04451019⟩
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  • Yang Li, Marina Briand, Karinne Miqueu, Elsa Anselmi, Emmanuel Magnier, et al.. Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals. Chemistry - A European Journal, 2024, 30 (10), pp.e202303545. ⟨10.1002/chem.202303545⟩. ⟨hal-04404468⟩
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  • Arnaud de Zordo-Banliat, Kevin Grollier, Nicolas Vanthuyne, Sébastien Floquet, Thierry Billard, et al.. Perfluoroalkyl Selenoxides, Selenones and Selenoximines: General Preparation and Properties. Angewandte Chemie International Edition, 2023, 62 (12), ⟨10.1002/anie.202300951⟩. ⟨hal-04046563⟩
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  • Camille Banoun, Flavien Bourdreux, Guillaume Dagousset. Highly selective γ-alkoxylation, γ-amination and γ-alkylation of unbiased enals by means of photoredox catalysis. Chemical Communications, 2023, 59 (6), pp.760-763. ⟨10.1039/d2cc05749b⟩. ⟨hal-03961871⟩
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  • Camille Banoun, Emmanuel Magnier, Guillaume Dagousset. Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C-O Bond Formation. SYNLETT, 2023, ⟨10.1055/a-2131-4126⟩. ⟨hal-04231477⟩
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  • Emmanuel Magnier, Guillaume Dagousset. Fluorine and chalcogen atoms: An association of benefactors. Tetrahedron, 2022, 113, pp.132754. ⟨10.1016/j.tet.2022.132754⟩. ⟨hal-03687520⟩
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  • Thibaut Duhail, Mingxiang Zhu, Coralie Rombault, Guillaume Dagousset, Samir Messaoudi, et al.. Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202200173⟩. ⟨hal-03668549⟩
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  • Arnaud de Zordo-Banliat, Kevin Grollier, Jordan Vigier, Erwann Jeanneau, Guillaume Dagousset, et al.. Vinylic Trifluoromethylselenolation via Pd‐Catalyzed C−H Activation. Chemistry - A European Journal, In press, ⟨10.1002/chem.202202299⟩. ⟨hal-03784203⟩
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  • Marina Briand, Linh Thai, Flavien Bourdreux, Nicolas Vanthuyne, Xavier Moreau, et al.. Remote Radical Trifluoromethylation: A Unified Approach to the Selective Synthesis of γ-Trifluoromethyl α,β-Unsaturated Carbonyl Compounds. Organic Letters, 2022, 24 (51), pp.9375-9380. ⟨10.1021/acs.orglett.2c03676⟩. ⟨hal-03936896⟩
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  • Armando Talavera-Alemán, Guillaume Dagousset, Christine Thomassigny. Synthesis of α-trifluoromethyl piperidine derivatives from tetrahydropyridines via nucleophilic trifluoromethylation of pyridinium cations. Journal of Fluorine Chemistry, 2021, 252, pp.109904. ⟨10.1016/j.jfluchem.2021.109904⟩. ⟨hal-03437405⟩
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  • Kevin Grollier, Emmanuel Chefdeville, Arnaud de Zordo-Banliat, Bruce Pegot, Guillaume Dagousset, et al.. Fe-mediated nucleophilic trifluoromethylselenolation of activated alkyl bromides via umpolung reactivity of trifluoromethyl tolueneselenosulfinate. Tetrahedron, 2021, 100, pp.132498. ⟨10.1016/j.tet.2021.132498⟩. ⟨hal-03834329⟩
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  • Thibaut Duhail, Tommaso Bortolato, Javier Mateos, Elsa Anselmi, Benson Jelier, et al.. Radical α-Trifluoromethoxylation of Ketones under Batch and Flow Conditions by Means of Organic Photoredox Catalysis. Organic Letters, 2021, 23 (18), pp.7088-7093. ⟨10.1021/acs.orglett.1c02494⟩. ⟨hal-03380290⟩
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  • Armando Talavera-Alemán, Jérome Marrot, Guillaume Dagousset, Christine Thomassigny. Synthesis of Nitrogen- and Oxygen-Containing Heterocycles by Prins Cyclization in Continuous Flow. Synthesis: Journal of Synthetic Organic Chemistry, 2021, 53 (8), pp.1478-1488. ⟨10.1055/s-0040-1705988⟩. ⟨hal-03125948⟩
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  • Kevin Grollier, Arnaud de Zordo‐banliat, Flavien Bourdreux, Bruce Pegot, Guillaume Dagousset, et al.. (Trifluoromethylselenyl)methylchalcogenyl as emerging fluorinated groups: synthesis under photoredox catalysis and determination of the lipophilicity. Chemistry - A European Journal, 2021, 27 (19), pp.6028-6033. ⟨10.1002/chem.202100053⟩. ⟨hal-03407531⟩
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  • Camille Banoun, Flavien Bourdreux, Emmanuel Magnier, Guillaume Dagousset. Intermolecular C-O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds. Organic Letters, 2021, 23 (22), pp.8926-8930. ⟨10.1021/acs.orglett.1c03444⟩. ⟨hal-03487851⟩
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  • Anne‐laure Barthelemy, F. Bourdreux, Guillaume Dagousset, Emmanuel Magnier. Photoredox-Catalyzed Selective Synthesis of Allylic Perfluoroalkanes from Alkenes. Chemistry - A European Journal, 2020, 26 (45), pp.10213-10216. ⟨10.1002/chem.202002046⟩. ⟨hal-02992795⟩
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  • Simon Rössler, Benson Jelier, Emmanuel Magnier, Guillaume Dagousset, Erick Carreira, et al.. Pyridinium Salts as Redox‐Active Functional Group Transfer Reagents. Angewandte Chemie International Edition, 2020, 59 (24), pp.9264-9280. ⟨10.1002/anie.201911660⟩. ⟨hal-02992788⟩
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  • Anne-Laure Barthelemy, Victor Certal, Guillaume Dagousset, Elsa Anselmi, Luc Bertin, et al.. Optimization and Gram-Scale Preparation of S -Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF 3 Group. Organic Process Research and Development, 2020, 24 (5), pp.704-712. ⟨10.1021/acs.oprd.9b00403⟩. ⟨hal-03097860⟩
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  • Anne-Laure Barthelemy, Guillaume Dagousset, Emmanuel Magnier. Metal-Free Visible-Light-Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow. European Journal of Organic Chemistry, 2020, 2020 (10), pp.1429-1432. ⟨10.1002/ejoc.201901252⟩. ⟨hal-02992749⟩
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  • Arnaud de Zordo-Banliat, Lucas Barthélémy, Flavien Bourdreux, Béatrice N. Tuccio, Guillaume Dagousset, et al.. Visible-Light-Induced Metal-Free Trifluoromethylselenolation of Electron-Rich Heteroarenes Using the Nucleophilic Me4N][SeCF3] Reagent. European Journal of Organic Chemistry, 2020, 2020 (4), pp.506-509. ⟨10.1002/ejoc.201901793⟩. ⟨hal-02861697⟩
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  • Christiane André-Barrès, Jacques Lalevée, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier, et al.. Spin trapping : la chasse aux intermédiaires radicalaires. L'Actualité Chimique, 2019. ⟨hal-03011793⟩
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  • Guillaume Levitre, Guillaume Dagousset, Elsa Anselmi, Béatrice Tuccio, Emmanuel Magnier, et al.. Four-Component Photoredox-Mediated Azidoalkoxy-trifluoromethylation of Alkenes. Organic Letters, 2019, 21 (15), pp.6005-6010. ⟨10.1021/acs.orglett.9b02152⟩. ⟨hal-02347070⟩
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  • Anne-Laure Barthelemy, Béatrice Tuccio, Emmanuel Magnier, Guillaume Dagousset. Intermolecular Trapping of Alkoxyl Radicals with Alkenes: A New Route to Ether Synthesis. SYNLETT, 2019, 30 (13), pp.1489-1495. ⟨10.1055/s-0037-1611785⟩. ⟨hal-02347568⟩
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  • Mingxiang Zhu, Guillaume Dagousset, Mouad Alami, Emmanuel Magnier, Samir Messaoudi. Ni/Photoredox-Dual-Catalyzed Functionalization of 1-Thiosugars. Organic Letters, 2019, 21 (13), pp.5132-5137. ⟨10.1021/acs.orglett.9b01730⟩. ⟨hal-02396639⟩
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  • Anne-Laure Barthelemy, Emmanuel Magnier, Guillaume Dagousset. Direct Trifluoromethylthiolation Reactions Involving Radical Processes. Synthesis: Journal of Synthetic Organic Chemistry, 2018, 50 (24), pp.4765-4776. ⟨10.1055/s-0037-1611278⟩. ⟨hal-02347500⟩
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  • Slim Chaabouni, Jean-François Lohier, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. One-Pot Synthesis of Aryl- and Alkyl S -Perfluoroalkylated NH -Sulfoximines from Sulfides. Chemistry - A European Journal, 2018, 24 (64), pp.17006-17010. ⟨10.1002/chem.201805055⟩. ⟨hal-01926255⟩
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  • Anne-Laure Barthelemy, Beátrice Tuccio, Emmanuel Magnier, Guillaume Dagousset. Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti-Markovnikov Alkoxylation Reactions. Angewandte Chemie International Edition, 2018, 57 (42), pp.13790--13794. ⟨10.1002/anie.201806522⟩. ⟨hal-02091883⟩
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  • Guillaume Dagousset, Cédric Simon, Elsa Anselmi, Béatrice Tuccio, Thierry Billard, et al.. Generation of the SCF3 radical by photoredox catalysis: Intra- and intermolecular carbotrifluoromethylthiolation of alkenes. Chemistry - A European Journal, 2017, 23 (18), pp.4282-4286. ⟨10.1002/chem.201700734⟩. ⟨hal-01606062⟩
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  • Marion Daniel, Guillaume Dagousset, Patrick Diter, Pierre-André Klein, Beátrice Tuccio, et al.. Fluorinated sulfilimino iminiums: a versatile source of perfluoroalkyl radicals under photoredox catalysis. Angewandte Chemie International Edition, 2017, ⟨10.1002/anie.201700290⟩. ⟨hal-02113752⟩
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  • Riadh Zriba, Alaric Desmarchelier, Frederic Cadoret, Sebastien Bouvet, Anne-Laure Barthelemy, et al.. Dichlorotrifluoromethoxyacetic acid: Preparation and reactivity. Molecules, 2017, 22 (6), pp.1-7. ⟨10.3390/molecules22060966⟩. ⟨hal-01606613⟩
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  • Lucie Jarrige, Aude Carboni, Guillaume Dagousset, Guillaume Levitre, Emmanuel Magnier, et al.. Photoredox-Catalyzed Three-Component Tandem Process: An Assembly of Complex Trifluoromethylated Phthalans and Isoindolines. Organic Letters, 2016, 18 (12), pp.2906-2909. ⟨10.1021/acs.orglett.6b01257⟩. ⟨hal-02347519⟩
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  • Aude Carboni, Guillaume Dagousset, Emmanuel Magnier, Geraldine Masson. Three-Component Photoredox-Mediated Chloro-, Bromo-, or Iodotrifluoromethylation of Alkenes. Synthesis: Journal of Synthetic Organic Chemistry, 2015, 47 (16), pp.2439-2445. ⟨10.1055/s-0034-1378715⟩. ⟨hal-02347532⟩
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  • Thibaut Courant, Guillaume Dagousset, Géraldine Masson. Enamide Derivatives: Versatile Building Blocks for Total Synthesis. Synthesis: Journal of Synthetic Organic Chemistry, 2015, 47 (13), pp.1799-1826. ⟨10.1055/s-0034-1378706⟩. ⟨hal-01178961⟩
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  • Aude Carboni, Guillaume Dagousset, Emmanuel Magnier, Géraldine Masson. One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis.. Chemical Communications, 2014, 50 (91), pp.14197-14200. ⟨hal-01104322⟩
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  • Guillaume Dagousset, Cyril François, Thierry Leόn, Romain Blanc, Elodie Sansiaume-Dagousset, et al.. Preparation of Functionalized Lithium, Magnesium, Aluminum, Zinc, Manganese­, and Indium Organometallics from Functionalized Organic Halides. Synthesis: Journal of Synthetic Organic Chemistry, 2014, 46 (23), pp.3133-3171. ⟨10.1055/s-0034-1378672⟩. ⟨hal-02347550⟩
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  • Guillaume Dagousset, Aude Carboni, Emmanuel Magnier, Géraldine Masson. Photoredox-induced three-component azido- and aminotrifluoromethylation of alkenes.. Organic Letters, 2014, 16 (16), pp.4340-4343. ⟨10.1021/ol5021477⟩. ⟨hal-01065684⟩
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  • Guillaume Dagousset, William Erb, Jieping Zhu, Géraldine Masson. Phosphoric Acid catalyzed diastereo- and enantioselective synthesis of substituted 1,3-diaminotetralins.. Organic Letters, 2014, 16 (9), pp.2554-7. ⟨10.1021/ol500946w⟩. ⟨hal-00990947⟩
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  • Guillaume Dagousset, Kohei Moriya, Rasmus Mose, Guillaume Berionni, Konstantin Karaghiosoff, et al.. Diastereoselective Synthesis of Open-Chain Secondary Alkyllithium Compounds and Trapping Reactions with Electrophiles. Angewandte Chemie International Edition, 2014, 53 (5), pp.1425-1429. ⟨10.1002/anie.201308679⟩. ⟨hal-02347538⟩
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  • Aude Carboni, Guillaume Dagousset, Emmanuel Magnier, Géraldine Masson. Photoredox-induced three-component oxy-, amino-, and carbotrifluoromethylation of enecarbamates. Organic Letters, 2014, 16 (4), pp.1240-1243. ⟨10.1021/ol500374e⟩. ⟨hal-00966064⟩
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  • Stephanie Seel, Guillaume Dagousset, Tobias Thaler, Annette Frischmuth, Konstantin Karaghiosoff, et al.. Preparation of Stereodefined Secondary Alkyllithium Compounds. Chemistry - A European Journal, 2013, 19 (14), pp.4614-4622. ⟨10.1002/chem.201204076⟩. ⟨hal-02347556⟩
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  • Géraldine Masson, Claudia Lalli, Meryem Benohoud, Guillaume Dagousset. Catalytic enantioselective [4 + 2]-cycloaddition: a strategy to access aza-hexacycles.. Chemical Society Reviews, 2013, 42 (3), pp.902-23. ⟨10.1039/c2cs35370a⟩. ⟨hal-00807909⟩
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  • Guillaume Dagousset, Pascal Retailleau, Géraldine Masson, Jieping Zhu. Chiral phosphoric Acid-catalyzed enantioselective three-component povarov reaction using cyclic enethioureas as dienophiles: stereocontrolled access to enantioenriched hexahydropyrroloquinolines.. Chemistry - A European Journal, 2012, 18 (19), pp.5869-73. ⟨10.1002/chem.201200523⟩. ⟨hal-00705296⟩
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  • Guillaume Dagousset, Fleur Drouet, Géraldine Masson, Jieping Zhu. Chiral Brønsted acid-catalyzed enantioselective multicomponent Mannich reaction: synthesis of anti-1,3-diamines using enecarbamates as nucleophiles.. Organic Letters, 2009, 11 (23), pp.5546-9. ⟨10.1021/ol9023985⟩. ⟨hal-00451493⟩
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  • Hua Liu, Guillaume Dagousset, Géraldine Masson, Pascal Retailleau, Jieping Zhu. Chiral Brønsted acid-catalyzed enantioselective three-component Povarov reaction.. Journal of the American Chemical Society, 2009, 131 (13), pp.4598-9. ⟨10.1021/ja900806q⟩. ⟨hal-00375339⟩
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Communications dans un congrès6 document




    

  • Guillaume Dagousset. Photoredox Generation of Oxygen-Centered Radicals: -Alkoxylation and -Trifluoromethoxylation of Carbonyl Compounds. JCO 2022, Nov 2022, Palaiseau (Ecole Polytechnique), France. ⟨hal-04422779⟩
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  • Guillaume Dagousset. alpha-Trifluoromethoxylation de cétones en batch et en flux continu par catalyse organophotoredox. Colloque Français de la Chimie du Fluor (CFCF3), May 2022, Forges les Eaux, France. ⟨hal-04422764⟩
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  • Guillaume Dagousset. Photoredox-catalyzed difunctionalization of alkenes involving Carbon-, Sulfur-, and Oxygen-centered radicals. , Journée d’Automne de la Division de Chimie Organique, Dec 2018, Paris, France. ⟨hal-04422727⟩
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  • Slim Chaabouni, Lohier Jean-François, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. New and general access to S-perfluoroalkyl NH sulfoximines. 22nd International Symposium on fluorine chemistry, Jul 2018, Oxford, United Kingdom. ⟨hal-01828289⟩
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  • Guillaume Dagousset. Photoredox catalysis: a powerful tool to prepare perfluoroalkylated and trifluoromethylthiolated molecules. 22st International Symposium on Fluorine Chemistry (22stISFC), Jul 2018, Oxford, United Kingdom. ⟨hal-04422718⟩
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  • Slim Chaabouni, Lohier Jean-François, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. New and general access to S-perfluoroalkyl NH sulfoximines. Journée scientifique du labex CHARM3AT, Jun 2018, Cachan, France. ⟨hal-01828299⟩
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Autres publications1 document




    

  • Anne‐laure Barthelemy, Guillaume Dagousset, Emmanuel Magnier. Cover Feature: Metal‐Free Visible‐Light‐Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow (Eur. J. Org. Chem. 10/2020). 2019, pp.1190-1190. ⟨10.1002/ejoc.201901800⟩. ⟨hal-04417657⟩
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Thèses1 document




    

  • Guillaume Dagousset. Etude de la réaction de Povarov : synthèse énantiosélective de composés diaminés organocatalysée par des acides phosphoriques chiraux. Autre. Université Paris Sud - Paris XI, 2011. Français. ⟨NNT : 2011PA112274⟩. ⟨tel-00802712⟩
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