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Disciplines
Mots-clefs
ACETYLENES ACIDS ACTIVATION ALDEHYDES ALPHA-FLUOROSULFOXIMINES Adduit de spin Alcene Alkene Amides Aminoisoquinoline BROMIDES Copper Cross-coupling Fluorine Homogeneous catalysis Palladium Sulfoximine Sulfoximines Sulfur Synthetic methods
- Fluorine5
- Palladium3
- Sulfoximines3
- ACTIVATION2
- Copper2
- Cross-coupling2
- Homogeneous catalysis2
- Sulfoximine2
- Sulfur2
- Synthetic methods2
- ACETYLENES1
- ACIDS1
- ALDEHYDES1
- ALPHA-FLUOROSULFOXIMINES1
- Adduit de spin1
- Alcene1
- Alkene1
- Amides1
- Aminoisoquinoline1
- BROMIDES1
- Biaryls1
- CH-activation1
- Ccarbotrifluoromethylthiolation1
- Cobalt Catalyst1
- DIFLUOROMETHYLATION1
- Dienamides1
- Dienoic acids1
- Difluoromethylation1
- Disulfides1
- Dualphotocatalysis1
- ELECTROPHILIC CYCLIZATION1
- EPOXIDES1
- EPR1
- EPR spectroscopy1
- Electrophilic cyclization1
- FLUOROEPOXIDES1
- FUNGUS COROLLOSPORA-PULCHELLA1
- Fluorinated compounds1
- Fluorine·Heterocycles1
- Glycosides1
- HETEROCYCLES1
- Heck reaction1
- Heterocycle1
- Heterocycles1
- Hydroxymethanesulfinate1
- Hypervalent compounds1
- Hypervalent iodine1
- Indole-fused lactones1
- Intermédiaire radicalaire1
- Iodine1
- Iodocyclization1
- Iodolactonization1
- Ionic liquids1
- Isocoumarins1
- Ligands1
- Multiple bonds1
- Mycobacterium tuberculosis1
- Mécanisme de la réaction1
- Mécanisme réactionnel spin trapping1
- NUCLEOPHILES1
- Nmr spectrometry1
- Nucleophilic substitution1
- Organic solvent1
- Organofluorine compounds1
- Organome-tallic reagents1
- Oxygen heterocycles1
- Palladiumii1
- Paramagnetic resonance1
- Perfluoroalkyl sulfides1
- Photocatalyse1
- Photocatalysis1
- Photoredox catalysis1
- Pulchellalactam1
- REAGENT1
- REAGENTS1
- RECEPTOR1
- REGIOSELECTIVE SYNTHESIS1
- RPE1
- Radical1
- Radical intermediate1
- Radicals1
- Reaction mechanism1
- Regioselectively1
- Regioselectivity1
- Résonance paramagnétique électronique1
- S-arylsulfoximines1
- STRATEGY1
- Scale-up1
- Sodium1
- Solvant organique1
- Spectrométrie rmn1
- Spin adduct1
- Spin trapping1
- Stille reaction1
- Sulfides1
- Sulfones1
- Sulfoximines fluorées1
- Sulfur heterocycles1
- Synthon1
- TGA1
- Thioglycosides1
- Thiols1
- Trifluoromethoxy1
- Trifluoromethyl1
- Trifluoromethyl bromide1
- Trifluoromethylation1
- Trifluoromethylethers1
- Trifluoromethylthiolation1
- Trifluoromethylthiosaccharin1
- Vinyl sulfoxides1
- Vinylation1
- Ynamide1
Auteurs
Anselmi Elsa44
Magnier Emmanuel28
Dagousset Guillaume16
Barthelemy Anne-Laure7
Thibonnet Jérôme7
Diter Patrick6
Pegot Bruce6
Abarbri Mohamed6
Duhail Thibaut5
Briand Marina3
Chaabouni Slim3
Glachet Thomas3
Tuccio Béatrice3
Messaoudi Samir3
Reboul Vincent3
Blazejewski Jean-Claude2
Bouvet Sebastien2
Goujon Gabriel2
Hammoud Sokaina2
Kalim Jorna2
Kizirian Jean-Claude2
Le Thanh-Nghi2
Maaliki Carine2
Ngi Samuel Inack2
Simon Cédric2
Pégot Bruce2
Cuadros Sara2
Paut Julien2
Miqueu Karinne2
Petrignet J.2
André-Barrès Christiane2
Jean-François Lohier2
Marrot Jérôme2
Billard Thierry2
Babichenko Liudmila N.1
Bahlaouan Zineb1
Baldon Simone1
Belkadi Mohamed1
Bennai Nedjwa1
Bernardelli Patrick1
Bertin Luc1
Cadoret Frederic1
Certal Victor1
Champciaux Bastien1
Cherry K.1
Cherry Khalil1
Courtes Philippe1
Dagousset Guillaume1
Dell'Amico Luca1
Desmarchelier Alaric1
Duchene A.1
Duchêne Alain1
El-Ahmad Youssef1
Fabien Laurence1
Hannedouche Jérôme1
Ibrahim Nada1
Inack Ngui Samuel1
Kesküla Carmen1
Langle-Lamandé Sandrine1
Leclerc Nathalie1
Levitre Guillaume1
Lipetskij Volidimir O.1
Marrot Jérôme C.1
Ngi S. Inack1
Pan Shulei1
Parrain Jean Luc1
Paut Julien1
Pietrasiak Ewa1
Poma Christian1
Pégot Bruce1
Raynaud Clement1
Retailleau Pascal1
Rombault Coralie1
Sanaa Hamdi1
Schio Laurent1
Soosaar Jan Erik1
Thanh Nghi Le -1
Toffano Martial1
Togni Antonio1
Tshepelevitsh Sofja1
Tuccio Béatrice1
Vincent Stéphane P.1
Vlasenko Yurii G.1
Wakselman Claude1
Wu Peng1
Yagupolskii Yurii1
Yagupolskii Yurii L.1
Zhu Mingxiang1
Zriba Riadh1
Togni Antonio1
Viljoen Albertus1
Bolm Carsten1
Kalim Jorna1
Li Yang1
Vo-Thanh Giang1
Mimoun Liliane1
Tuccio Béatrice1
Baldon Simone1
Pelosi Giorgio1
Lohier Jean-François1
Kremer Laurent1
Vanthuyne Nicolas1
Thiery Emilie1
Lamandé-Langle Sandrine1
Masson Geraldine1
Nicolas Cyril1
Guillot Régis1
Alami Mouâd1
Prieto Alexis1
Salgues Bruno1
Marrot Jerome1
Gillaizeau Isabelle1
Lalevée Jacques1
Leito Ivo1
Montigny Bénédicte1
Lõkov Märt1
Dell'Amico Luca1
Dell’amico Luca1
Tordeux Marc1
Duchêne Alain1
Gigmes Didier1
Sokolenko Liubov V.1
Auteurs de la structure
Revues
- European Journal of Organic Chemistry8
- Chemistry - A European Journal5
- Advanced Synthesis and Catalysis4
- Angewandte Chemie International Edition2
- Organic Process Research and Development2
- Synthesis: Journal of Synthetic Organic Chemistry2
- Chemical Science2
- Journal of Fluorine Chemistry1
- Molecules1
- Organic Letters1
Année de production
Institutions
Laboratoires
Départements
Équipes de recherche
44 documents
Articles dans une revue32 document
- Gabriel Goujon, Marina Briand, Nathalie Leclerc, Bruce Pégot, Guillaume Dagousset, et al.. Multigram-Scale Synthesis and Study of Reactivity of Two Difluoromethylating Reagents Based on Sulfoximine Skeletons. Organic Process Research and Development, 2025, ⟨10.1021/acs.oprd.5c00148⟩. ⟨hal-05143166⟩
- Simone Baldon, Julien Paut, Elsa Anselmi, Guillaume Dagousset, Béatrice Tuccio, et al.. Radical photochemical difluorosulfoximination of alkenes and propellanes. Chemical Science, In press, ⟨10.1039/d5sc01068c⟩. ⟨hal-05019725⟩
- Elsa Anselmi, Bénédicte Montigny, Märt Lõkov, Carmen Kesküla, Jan Erik Soosaar, et al.. Focus on Physico‐Chemical Properties of Sulfoximines: Acidity, Basicity and Lipophilicity. Chemistry - A European Journal, 2024, 31 (1), pp.e202402329. ⟨10.1002/chem.202402329⟩. ⟨hal-04814363⟩
- Peng Wu, Gabriel Goujon, Shulei Pan, Béatrice Tuccio, Bruce Pégot, et al.. Cyclic Sulfoximines as Methyl and Perdeuteromethyl Transfer Agents and Their Applications in Photoredox Catalysis. Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202412418⟩. ⟨hal-04785277⟩
- Julien Paut, Simone Baldon, Elsa Anselmi, Luca Dell'Amico, Guillaume Dagousset, et al.. Photocatalytic α‐Difluoroalkoxyketones Synthesis via Radical Intermolecular Alkoxylation of Difluoroenol Silyl Ethers. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400510⟩. ⟨hal-04680319⟩
- Marina Briand, Emmanuel Magnier, Elsa Anselmi, Guillaume Dagousset. Photocatalyzed One‐Pot Selective Synthesis of γ‐(per)fluoroalkenylated α,β‐Unsaturated Carbonyl Compounds. Advanced Synthesis and Catalysis, 2024, ⟨10.1002/adsc.202400462⟩. ⟨hal-04665645⟩
- Hamdi Sanaa, Liliane Mimoun, Pascal Retailleau, Elsa Anselmi, Cyril Nicolas, et al.. Cobalt‐catalyzed annulation of benzimidates or NH‐benzaldimines with ynamides: synthesis of 1‐alkoxy‐ and 1‐alkyl‐3‐aminoisoquinolines. Advanced Synthesis and Catalysis, 2024, 366, pp.2495-2500. ⟨10.1002/adsc.202400166⟩. ⟨hal-04578464⟩
- Sara Cuadros, Julien Paut, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier, et al.. Light‐Driven Synthesis and Functionalization of Bicycloalkanes, Cubanes and Related Bioisosteres. Angewandte Chemie International Edition, 2024, ⟨10.1002/anie.202317333⟩. ⟨hal-04451019⟩
- Yang Li, Marina Briand, Karinne Miqueu, Elsa Anselmi, Emmanuel Magnier, et al.. Electrophilic Fluorination of Silyl Dienol Ethers: a General and Selective Access to γ‐Fluoro Enals. Chemistry - A European Journal, 2024, 30 (10), pp.e202303545. ⟨10.1002/chem.202303545⟩. ⟨hal-04404468⟩
- Thibaut Duhail, Samir Messaoudi, Guillaume Dagousset, Jérôme Marrot, Christiane André-Barrès, et al.. Benzodithiazoles‐Sulfoximines: Preparation, Properties and Reactivities as Radical Perfluoroalkylating Agents. Advanced Synthesis and Catalysis, 2023, 365 (14), pp.2392-2399. ⟨10.1002/adsc.202300553⟩. ⟨hal-04161292⟩
- Thibaut Duhail, Jorna Kalim, Jérôme Marrot, Bruce Pégot, Emmanuel Magnier, et al.. Perfluoroalkylated Sulfoximines as Analogues of Togni Reagents: The Crucial Role of Fluorine Atoms for the Stability of Hypervalent Iodine Scaffolds. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202300963⟩. ⟨hal-04316672⟩
- Thibaut Duhail, Mingxiang Zhu, Coralie Rombault, Guillaume Dagousset, Samir Messaoudi, et al.. Dual Photocatalysis for the Straightforward Coupling of Thiosugars and Arylsulfoximines: Towards Unprecedented Cyclic Heteroatomic Structures. European Journal of Organic Chemistry, In press, ⟨10.1002/ejoc.202200173⟩. ⟨hal-03668549⟩
- Jorna Kalim, Thibaut Duhail, Ewa Pietrasiak, Elsa Anselmi, Emmanuel Magnier, et al.. Direct Trifluoromethylation of Alcohols Using a Hypervalent Iodosulfoximine Reagent. Chemistry - A European Journal, 2020, ⟨10.1002/chem.202005104⟩. ⟨hal-03121267⟩
- Anne-Laure Barthelemy, Victor Certal, Guillaume Dagousset, Elsa Anselmi, Luc Bertin, et al.. Optimization and Gram-Scale Preparation of S -Trifluoromethyl Sulfoximines and Sulfilimino Iminiums, Powerful Reagents for the Late Stage Introduction of the CF 3 Group. Organic Process Research and Development, 2020, 24 (5), pp.704-712. ⟨10.1021/acs.oprd.9b00403⟩. ⟨hal-03097860⟩
- Nedjwa Bennai, Nada Ibrahim, Jérôme C. Marrot, Mohamed Belkadi, Mouâd Alami, et al.. Synthesis of S-Trifluoromethyl S-Arylsulfoximine Thioglycosides through Pd-Catalyzed Migita Cross-Coupling. European Journal of Organic Chemistry, 2020, 2020 (31), pp.4972-4981. ⟨10.1002/ejoc.202000821⟩. ⟨hal-02938398⟩
- Jorna Kalim, Thibaut Duhail, Thanh-Nghi Le, Nicolas Vanthuyne, Elsa Anselmi, et al.. Merging hypervalent iodine and sulfoximine chemistry: a new electrophilic trifluoromethylation reagent. Chemical Science, 2019, 10 (45), pp.10516-10523. ⟨10.1039/c9sc04289j⟩. ⟨hal-02514618⟩
- Christiane André-Barrès, Jacques Lalevée, Elsa Anselmi, Guillaume Dagousset, Emmanuel Magnier, et al.. Spin trapping : la chasse aux intermédiaires radicalaires. L'Actualité Chimique, 2019. ⟨hal-03011793⟩
- Guillaume Levitre, Guillaume Dagousset, Elsa Anselmi, Béatrice Tuccio, Emmanuel Magnier, et al.. Four-Component Photoredox-Mediated Azidoalkoxy-trifluoromethylation of Alkenes. Organic Letters, 2019, 21 (15), pp.6005-6010. ⟨10.1021/acs.orglett.9b02152⟩. ⟨hal-02347070⟩
- Anne-Laure Barthelemy, Elsa Anselmi, Thanh-Nghi Le, Giang Vo-Thanh, Régis Guillot, et al.. Divergent Synthesis of 1,2-Benzo[ e ]thiazine and Benzo[ d ]thiazole Analogues Containing a S -Trifluoromethyl Sulfoximine Group: Preparation and New Properties of the Adachi Reagent. Journal of Organic Chemistry, 2019, 84 (7), pp.4086-4094. ⟨10.1021/acs.joc.9b00079⟩. ⟨hal-02093608⟩
- Anne-Laure Barthelemy, Alexis Prieto, Patrick Diter, Jérôme Hannedouche, Martial Toffano, et al.. Facile Preparation of Vinyl S -Trifluoromethyl N H Aryl Sulfoximines. European Journal of Organic Chemistry, 2018, 2018 (27-28), pp.3764-3770. ⟨10.1002/ejoc.201800324⟩. ⟨hal-02358294⟩
- Slim Chaabouni, Jean-François Lohier, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. One-Pot Synthesis of Aryl- and Alkyl S -Perfluoroalkylated NH -Sulfoximines from Sulfides. Chemistry - A European Journal, 2018, 24 (64), pp.17006-17010. ⟨10.1002/chem.201805055⟩. ⟨hal-01926255⟩
- Sokaina Hammoud, Elsa Anselmi, Khalil Cherry, Jean-Claude Kizirian, Jérôme Thibonnet. Synthesis and Reactivity of Oxazinoindolones via Regioselective 6- exo-dig Iodolactonization Reaction. European Journal of Organic Chemistry, 2018, 2018 (45), pp.6314-6327. ⟨10.1002/ejoc.201801167⟩. ⟨hal-02172429⟩
- Elsa Anselmi, Cédric Simon, Jerome Marrot, Patrick Bernardelli, Laurent Schio, et al.. Ionic Liquids for Fast and Solvent-Free Nucleophilic Trifluoromethylthiolation of Alkyl Halides and Alcohols. European Journal of Organic Chemistry, 2017, 2017 (42), pp.6319-6326. ⟨10.1002/ejoc.201701222⟩. ⟨hal-02624958⟩
- Riadh Zriba, Alaric Desmarchelier, Frederic Cadoret, Sebastien Bouvet, Anne-Laure Barthelemy, et al.. Dichlorotrifluoromethoxyacetic acid: Preparation and reactivity. Molecules, 2017, 22 (6), pp.1-7. ⟨10.3390/molecules22060966⟩. ⟨hal-01606613⟩
- Elsa Anselmi, Zineb Bahlaouan, Samuel Inack Ngi, Jean Luc Parrain, Emmanuel Magnier, et al.. Selective carboxylate directed ortho functionalization in copper catalyzed reactions of polyiodo aromatics: A straightforward preparation of 5,7-diiodo-1H-isochromen-1-ones. European Journal of Organic Chemistry, 2017, 41, pp.6131-6136. ⟨10.1002/ejoc.201700859⟩. ⟨hal-02619447⟩
- Guillaume Dagousset, Cédric Simon, Elsa Anselmi, Béatrice Tuccio, Thierry Billard, et al.. Generation of the SCF3 radical by photoredox catalysis: Intra- and intermolecular carbotrifluoromethylthiolation of alkenes. Chemistry - A European Journal, 2017, 23 (18), pp.4282-4286. ⟨10.1002/chem.201700734⟩. ⟨hal-01606062⟩
- Elsa Anselmi, K. Cherry, Carine Maaliki, S. Inack Ngi, A. Duchene, et al.. Two Novel and Simple Approaches to "CD45 Protein Tyrosine Phosphatase Inhibitor' (Z)-Pulchellalactam and Derivatives. Synthesis: Journal of Synthetic Organic Chemistry, 2016, 48 (9), pp.1407 - 1413. ⟨10.1055/s-0035-1561375⟩. ⟨hal-02637015⟩
- Elsa Anselmi, - Thanh Nghi Le, Sebastien Bouvet, Patrick Diter, Bruce Pegot, et al.. Synthesis of N-Alkenyl and N-Alkynyl S-Perfluoroalkylated Sulfoximines by Copper Catalysis. European Journal of Organic Chemistry, 2016, 25, pp.4423 - 4428. ⟨10.1002/ejoc.201600649⟩. ⟨hal-02631721⟩
- Liubov V. Sokolenko, Yurii L. Yagupolskii, Yurii G. Vlasenko, Liudmila N. Babichenko, Volidimir O. Lipetskij, et al.. Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction. Tetrahedron Letters, 2015, 56 (10), pp.1259-1262. ⟨10.1016/j.tetlet.2015.01.136⟩. ⟨hal-01170057⟩
- Elsa Anselmi, Mohamed Abarbri, Alain Duchêne, Sandrine Lamandé-Langle, Jérôme Thibonnet. Complete assignment of 1 H and 13C NMR spectra of 1, 2, 4-trisubstituted pyrroles. Journal of Spectroscopy, 2013, 2013, 146541 / 7p. ⟨10.1155/2013/146541⟩. ⟨hal-01524648⟩
- Elsa Anselmi, Mohamed Abarbri, Alain Duchêne, Sandrine Langle-Lamandé, Jérôme Thibonnet. Efficient Synthesis of Substituted Styrenes and Biaryls (or Heteroaryls) with Regioselective Reactions of ortho-, meta-, and para-Bromobenzyl Bromide. Synthesis: Journal of Synthetic Organic Chemistry, 2012, 44 (13), pp.2023-2040. ⟨10.1055/s-0031-1290987⟩. ⟨hal-02650697⟩
- Marc Tordeux, Elsa Anselmi, Jean-Claude Blazejewski, Claude Wakselman. Perfluoroalkylation of aliphatic thiols in the presence of sodium hydroxymethanesulfinate. Journal of Fluorine Chemistry, 2000, 105, pp.41. ⟨10.1016/S0022-1139(00)00286-4⟩. ⟨hal-00094982⟩
Communications dans un congrès6 document
- Elsa Anselmi. Benzodithiazoles-sulfoximines : syntheses of new powerful radical fluoroalkylating reagents. 23TH International Symposium of Fluorine Chemistry, Jul 2023, Québec, Canada. ⟨hal-04422786⟩
- Elsa Anselmi. Synthèse de sulfoximines perfluorées hautement fonctionnalisées. GECO 60, Aug 2019, Obernai, France. ⟨hal-04422740⟩
- Elsa Anselmi. New access to s-perfluoroalkylated sulfoximines and their functionalization. 10ème Conférence Internationale de Chimie Toulouse-Kiev (ICTK - 10), Jun 2019, toulouse, France. ⟨hal-04422737⟩
- Elsa Anselmi. High functionalization of S-perfluorinated sulfoximines. Progress in Organofluorine Chemistry, Le Studium Conferences, Oct 2018, Orléans, France. ⟨hal-04422729⟩
- Slim Chaabouni, Lohier Jean-François, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. New and general access to S-perfluoroalkyl NH sulfoximines. 22nd International Symposium on fluorine chemistry, Jul 2018, Oxford, United Kingdom. ⟨hal-01828289⟩
- Slim Chaabouni, Lohier Jean-François, Anne-Laure Barthelemy, Thomas Glachet, Elsa Anselmi, et al.. New and general access to S-perfluoroalkyl NH sulfoximines. Journée scientifique du labex CHARM3AT, Jun 2018, Cachan, France. ⟨hal-01828299⟩
Poster de conférence6 document
- Elsa Anselmi. Hypervalent Iodosulfoximines synthesis - An access to new perfluoroalkylating reagents. Journées de Chimie Organique, Nov 2022, Palaiseau, France. . ⟨hal-04422894⟩
- Sokaina Hammoud, Carine Maaliki, Bastien Champciaux, Albertus Viljoen, Clement Raynaud, et al.. Synthesis and evaluation of heterocycle structures as potential inhibitors of Mycobacterium tuberculosis. Journées de Chimie Organique, Nov 2022, Palaiseau (Ecole Polytechnique), France. ⟨hal-05019003⟩
- Elsa Anselmi. Palladium versus Nickel dual catalysis: two routes for coupling ortho-iodoperfluorosulfoximines with thiosugars. Colloque Français de Chimie du Fluor CFCF, May 2022, Forges les Eaux, France. ⟨hal-04422891⟩
- Elsa Anselmi. Study of new trifluoromethylation reactions under photoredox catalysis. Journée CHARMMAT, Oct 2021, Saclay, France. ⟨hal-04422848⟩
- Samuel Inack Ngui, J. Petrignet, Elsa Anselmi, Jérôme Thibonnet, Mohamed Abarbri. Cuprocatalyzed synthesis of lactones. Applications in total synthesis. JCO 2013 - Journées de Chimie Organique, Sep 2013, Palaiseau, France. 2013. ⟨hal-02803282⟩
- Samuel Inack Ngi, J. Petrignet, Elsa Anselmi, Mohamed Abarbri, Jérôme Thibonnet. Synthèse cuprocatalysée de lactones. Applications en synthèse totale. Journées de la section régionale Centre-Ouest Société Chimique de France, Dec 2012, Poitiers, France. 2012. ⟨hal-02810266⟩